Faculty Profile
Mike Richmond
Title
Professor
Department
Chemistry
College
College of Science
-
Chemistry Building366
- cobalt@unt.edu
- (940) 565-3548
- (940) 565-2713
Curriculum Vitae
Education
PhD, University of Alabama, 1983.
Major: Chemistry
Degree Specialization: Organic Chemistry
Dissertation Title: "Catalytic Studies Using Homogeneous and Heterogeneous Inorganic Catalysts and Synthesis of Potential Cancer Chemotherapeutic Agents"
BS, State University of New York, College at Fredonia, 1980.
Major: Chemistry
Current Scheduled Teaching*
CHEM 5380.002, Organic Chemistry, Spring 2024 Syllabus
* Texas Education Code 51.974 (HB 2504) requires each institution of higher education to make available to the public, a syllabus for undergraduate lecture courses offered for credit by the institution.
Previous Scheduled Teaching*
CHEM 6950.768, Doctoral Dissertation, Spring 2023
CHEM 6950.768, Doctoral Dissertation, Fall 2022
CHEM 2380.212, Organic Chemistry, Fall 2022
CHEM 6950.768, Doctoral Dissertation, Spring 2022
CHEM 6940.768, Individual Research, Spring 2022
CHEM 6950.768, Doctoral Dissertation, Fall 2021
CHEM 6940.768, Individual Research, Fall 2021
CHEM 2380.212, Organic Chemistry, Fall 2021 Syllabus
CHEM 6950.768, Doctoral Dissertation, Spring 2021
CHEM 6940.768, Individual Research, Spring 2021
CHEM 6950.768, Doctoral Dissertation, Fall 2020
CHEM 6940.768, Individual Research, Fall 2020
CHEM 2380.212, Organic Chemistry, Fall 2020
CHEM 6950.768, Doctoral Dissertation, Spring 2020
CHEM 6940.768, Individual Research, Spring 2020
CHEM 5380.002, Organic Chemistry, Spring 2020 Syllabus
CHEM 6950.768, Doctoral Dissertation, Fall 2019
CHEM 6940.768, Individual Research, Fall 2019
CHEM 3602.301, Laboratory for Organic Chemistry, Fall 2019 Syllabus
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2019 Syllabus
CHEM 3601.211, Organic Chemistry, Fall 2019
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2019
CHEM 6950.768, Doctoral Dissertation, Summer 5W1 2019
CHEM 6950.768, Doctoral Dissertation, Spring 2019
CHEM 6940.768, Individual Research, Spring 2019
CHEM 5380.002, Organic Chemistry, Spring 2019 SPOT
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2019
CHEM 6950.768, Doctoral Dissertation, Fall 2018
CHEM 6940.768, Individual Research, Fall 2018
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2018
CHEM 3601.211, Organic Chemistry, Fall 2018 Syllabus
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2018
CHEM 6950.768, Doctoral Dissertation, Spring 2018
CHEM 6940.768, Individual Research, Spring 2018
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2018
CHEM 6950.768, Doctoral Dissertation, Fall 2017
CHEM 6940.768, Individual Research, Fall 2017
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2017 Syllabus
CHEM 3601.211, Organic Chemistry, Fall 2017 Syllabus
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2017
CHEM 6940.768, Individual Research, Spring 2017
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2017
CHEM 6940.768, Individual Research, Fall 2016
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2016
CHEM 3601.211, Organic Chemistry, Fall 2016
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2016
CHEM 6940.768, Individual Research, Spring 2016
CHEM 5380.002, Organic Chemistry, Spring 2016 SPOT
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2016
CHEM 6940.768, Individual Research, Fall 2015
CHEM 3602.301, Laboratory for Organic Chemistry, Fall 2015
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2015
CHEM 3601.211, Organic Chemistry, Fall 2015
CHEM 6940.768, Individual Research, Spring 2015
CHEM 5950.768, Master's Thesis, Spring 2015
CHEM 5380.002, Organic Chemistry, Spring 2015
CHEM 6950.768, Doctoral Dissertation, Fall 2014
CHEM 6940.768, Individual Research, Fall 2014
CHEM 3602.301, Laboratory for Organic Chemistry, Fall 2014
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2014
CHEM 5950.768, Master's Thesis, Fall 2014
CHEM 3601.001, Organic Chemistry, Fall 2014 Syllabus
CHEM 3601.211, Organic Chemistry, Fall 2014
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2014
CHEM 6950.768, Doctoral Dissertation, Spring 2014
CHEM 6940.768, Individual Research, Spring 2014
CHEM 5950.768, Master's Thesis, Spring 2014
CHEM 5380.002, Organic Chemistry, Spring 2014
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2014
CHEM 4900.718, Special Problems, Spring 2014
CHEM 6950.768, Doctoral Dissertation, Fall 2013
CHEM 6940.768, Individual Research, Fall 2013
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2013
CHEM 5950.768, Master's Thesis, Fall 2013
CHEM 3601.001, Organic Chemistry, Fall 2013 Syllabus
CHEM 3601.211, Organic Chemistry, Fall 2013 Syllabus
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2013
CHEM 6940.768, Individual Research, Summer 5W1 2013
CHEM 6950.768, Doctoral Dissertation, Spring 2013
CHEM 6940.768, Individual Research, Spring 2013
CHEM 5380.002, Organic Chemistry, Spring 2013
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2013
CHEM 6950.768, Doctoral Dissertation, Fall 2012
CHEM 6940.768, Individual Research, Fall 2012
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2012
CHEM 5950.768, Master's Thesis, Fall 2012
CHEM 3601.001, Organic Chemistry, Fall 2012 Syllabus
CHEM 3601.211, Organic Chemistry, Fall 2012 Syllabus
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2012
CHEM 6940.768, Individual Research, Spring 2012
CHEM 5950.768, Master's Thesis, Spring 2012
CHEM 5380.002, Organic Chemistry, Spring 2012
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2012
CHEM 6940.768, Individual Research, Fall 2011
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2011
CHEM 5950.768, Master's Thesis, Fall 2011
CHEM 3601.001, Organic Chemistry, Fall 2011
CHEM 3601.211, Organic Chemistry, Fall 2011
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2011
CHEM 6940.768, Individual Research, Spring 2011
CHEM 5950.768, Master's Thesis, Spring 2011
CHEM 5380.002, Organic Chemistry, Spring 2011
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2011
CHEM 6940.768, Individual Research, Fall 2010
CHEM 3602.302, Laboratory for Organic Chemistry, Fall 2010
CHEM 5950.768, Master's Thesis, Fall 2010
CHEM 3601.001, Organic Chemistry, Fall 2010
CHEM 3601.211, Organic Chemistry, Fall 2010
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2010
CHEM 6950.768, Doctoral Dissertation, Summer 5W1 2010
CHEM 6950.768, Doctoral Dissertation, Spring 2010
CHEM 6940.768, Individual Research, Spring 2010
CHEM 5950.768, Master's Thesis, Spring 2010
CHEM 5380.002, Organic Chemistry, Spring 2010
CHEM 6950.768, Doctoral Dissertation, Fall 2009
CHEM 6940.768, Individual Research, Fall 2009
CHEM 5950.768, Master's Thesis, Fall 2009
CHEM 6940.768, Individual Research, Spring 2009
CHEM 5950.768, Master's Thesis, Spring 2009
CHEM 5380.002, Organic Chemistry, Spring 2009
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2009
CHEM 4900.718, Special Problems, Spring 2009
CHEM 6940.768, Individual Research, Fall 2008
CHEM 5950.768, Master's Thesis, Fall 2008
CHEM 3220.001, Organic Chemistry Laboratory, Fall 2008
CHEM 3220.301, Organic Chemistry Laboratory, Fall 2008
CHEM 3220.302, Organic Chemistry Laboratory, Fall 2008
CHEM 3220.303, Organic Chemistry Laboratory, Fall 2008
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2008
CHEM 6940.768, Individual Research, Summer 5W2 2008
CHEM 6940.768, Individual Research, Summer 5W1 2008
CHEM 6950.768, Doctoral Dissertation, Spring 2008
CHEM 6940.768, Individual Research, Spring 2008
CHEM 5950.768, Master's Thesis, Spring 2008
CHEM 5380.002, Organic Chemistry, Spring 2008
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2008
CHEM 4900.718, Special Problems, Spring 2008
CHEM 6950.768, Doctoral Dissertation, Fall 2007
CHEM 6940.768, Individual Research, Fall 2007
CHEM 2370.002, Organic Chemistry, Fall 2007
CHEM 2370.212, Organic Chemistry, Fall 2007
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2007
CHEM 6950.768, Doctoral Dissertation, Summer 5W1 2007
CHEM 6940.768, Individual Research, Summer 5W2 2007
CHEM 6940.768, Individual Research, Summer 5W1 2007
CHEM 3210.001, Organic Chemistry Laboratory, Summer 5W1 2007
CHEM 3210.301, Organic Chemistry Laboratory, Summer 5W1 2007
CHEM 3210.302, Organic Chemistry Laboratory, Summer 5W1 2007
CHEM 3220.001, Organic Chemistry Laboratory, Summer 5W2 2007
CHEM 3220.301, Organic Chemistry Laboratory, Summer 5W2 2007
CHEM 3220.302, Organic Chemistry Laboratory, Summer 5W2 2007
CHEM 3220.303, Organic Chemistry Laboratory, Summer 5W2 2007
CHEM 6950.768, Doctoral Dissertation, Spring 2007
CHEM 6940.768, Individual Research, Spring 2007
CHEM 5380.002, Organic Chemistry, Spring 2007
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2007
CHEM 4900.718, Special Problems, Spring 2007
CHEM 6950.768, Doctoral Dissertation, Fall 2006
CHEM 6940.768, Individual Research, Fall 2006
CHEM 2370.213, Organic Chemistry, Fall 2006
CHEM 3210.001, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.002, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.301, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.302, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.304, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.305, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.306, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.307, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.309, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.310, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.311, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.312, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.313, Organic Chemistry Laboratory, Fall 2006
CHEM 3210.314, Organic Chemistry Laboratory, Fall 2006
CHEM 3220.001, Organic Chemistry Laboratory, Fall 2006
CHEM 3220.301, Organic Chemistry Laboratory, Fall 2006
CHEM 3220.302, Organic Chemistry Laboratory, Fall 2006
CHEM 3220.303, Organic Chemistry Laboratory, Fall 2006
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2006
CHEM 4900.718, Special Problems, Fall 2006
CHEM 6950.768, Doctoral Dissertation, Summer 5W2 2006
CHEM 6950.768, Doctoral Dissertation, Summer 5W1 2006
CHEM 6940.768, Individual Research, Summer 5W1 2006
CHEM 6940.768, Individual Research, Summer 5W2 2006
CHEM 5950.768, Master's Thesis, Summer 5W2 2006
CHEM 5950.768, Master's Thesis, Summer 5W1 2006
CHEM 2370.001, Organic Chemistry, Summer 5W1 2006
CHEM 2380.001, Organic Chemistry, Summer 5W2 2006
CHEM 3210.001, Organic Chemistry Laboratory, Summer 5W1 2006
CHEM 3210.301, Organic Chemistry Laboratory, Summer 5W1 2006
CHEM 3210.302, Organic Chemistry Laboratory, Summer 5W1 2006
CHEM 3220.001, Organic Chemistry Laboratory, Summer 5W2 2006
CHEM 3220.301, Organic Chemistry Laboratory, Summer 5W2 2006
CHEM 3220.302, Organic Chemistry Laboratory, Summer 5W2 2006
CHEM 3220.303, Organic Chemistry Laboratory, Summer 5W2 2006
CHEM 4900.718, Special Problems, Summer 5W2 2006
CHEM 4900.718, Special Problems, Summer 5W1 2006
CHEM 6950.768, Doctoral Dissertation, Spring 2006
CHEM 6940.768, Individual Research, Spring 2006
CHEM 5950.768, Master's Thesis, Spring 2006
CHEM 5380.002, Organic Chemistry, Spring 2006
CHEM 5380.200, Organic Chemistry, Spring 2006
CHEM 5380.300, Organic Chemistry, Spring 2006
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2006
CHEM 4900.718, Special Problems, Spring 2006
CHEM 6950.768, Doctoral Dissertation, Fall 2005
CHEM 6940.768, Individual Research, Fall 2005
CHEM 5950.768, Master's Thesis, Fall 2005
CHEM 2370.003, Organic Chemistry, Fall 2005
CHEM 2370.213, Organic Chemistry, Fall 2005
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2005
CHEM 6950.768, Doctoral Dissertation, Summer 5W1 2005
CHEM 6940.768, Individual Research, Summer 5W1 2005
CHEM 6940.768, Individual Research, Summer 5W2 2005
CHEM 5950.768, Master's Thesis, Summer 5W2 2005
CHEM 2380.001, Organic Chemistry, Summer 5W2 2005
CHEM 3210.001, Organic Chemistry Laboratory, Summer 5W1 2005
CHEM 3210.301, Organic Chemistry Laboratory, Summer 5W1 2005
CHEM 3210.302, Organic Chemistry Laboratory, Summer 5W1 2005
CHEM 3220.001, Organic Chemistry Laboratory, Summer 5W2 2005
CHEM 3220.301, Organic Chemistry Laboratory, Summer 5W2 2005
CHEM 3220.302, Organic Chemistry Laboratory, Summer 5W2 2005
CHEM 6950.768, Doctoral Dissertation, Spring 2005
CHEM 6940.768, Individual Research, Spring 2005
CHEM 2900.718, Introduction to Chemical Research, Spring 2005
CHEM 5380.002, Organic Chemistry, Spring 2005
CHEM 5380.200, Organic Chemistry, Spring 2005
CHEM 6010.718, Seminar for Doctoral Candidates, Spring 2005
CHEM 4900.718, Special Problems, Spring 2005
CHEM 6950.768, Doctoral Dissertation, Fall 2004
CHEM 6940.768, Individual Research, Fall 2004
CHEM 2370.003, Organic Chemistry, Fall 2004
CHEM 2370.213, Organic Chemistry, Fall 2004
CHEM 6010.718, Seminar for Doctoral Candidates, Fall 2004
* Texas Education Code 51.974 (HB 2504) requires each institution of higher education to make available to the public, a syllabus for undergraduate lecture courses offered for credit by the institution.
Published Publications
Published Intellectual Contributions
Conference Proceeding
Metz, J. M., Richmond, M. G., Nesterov, V. (2012). Synthesis and reactivity studies on the polynuclear metal cluster Os-3 (CO)(10)[1, 2-p-tolylS (C6H4) PPh2]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 243, .
Keith, J. M., Hall, M. B., Richmond, M. G. (2010). Mechanistic investigations of reversible intramolecular ortho metalation in Os3 (CO) 10 (dppm). ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 239, .
Kandala, S., Richmond, M. G. (2007). Reversible isomerization of a diphosphine ligand and regiospecific CH and PC bond cleavage reactivity in the triosmium cluster Os3 (CO) 10 (bmf). ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 233, 744--744.
Glass, D., Wiedenfeld, D., Minton, M., Richmond, M. G., Wu, G. (2005). The Use of Emission Spectroscopy to Determine Electron-Transfer Rates and to Characterize the Excited States of Ligands and Metal Complexes. The 60th Northwest Regional Meeting.
WANG, S., RICHMOND, M., SCHWARTZ, M. (1990). LIGAND EFFECTS ON PI-BONDING IN TUNGSTEN PENTACARBONYLS. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 199, 48--INOR.
LEE, S., RICHMOND, M., COWLEY, A., NUNN, C. (1989). SYNTHESIS AND CHARACTERIZATION OF ANIONIC CYCLOPENTADIENYL RHENIUM COMPLEXES-RING ATTACK VS METALATION. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 197, 436--INOR.
DON, M., RICHMOND, M., WATSON, W., NAGL, A. (1989). SYNTHESIS AND REACTIVITY OF ARACHNO FE2/PT CHALCOGENIDE CLUSTERS. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 197, 273--INOR.
Schulman, C. L., DON, M., RICHMOND, M. (1989). SYNTHESIS, STRUCTURE, AND SOLUTION DYNAMICS OF CO4 (CO) 8 (DMPE)(MU-4-PPH) 2. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 197, 329--INOR.
HWANG, S., DUMOND, D., RICHMOND, M. (1989). TRANSIENT METAL FORMYLS AS A ROUTE TO PARAMAGNETIC ORGANOMETALLIC COMPLEXES. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 197, 328--INOR.
Journal Article
Bhowmik, M. L., Al Mamun, M. A., Ghosh, S., Nesterov, V. N., Richmond, M. G., Kabir, S. E., Roesky, H. W. (2023). Polynuclear ruthenium clusters containing stibine, stibene, and stibinidene ligands. Journal of Organometallic Chemistry. 984, 122574. Elsevier.
Orton, G. R., Ghosh, S., Alker, L., Sarker, J. C., Pugh, D., Richmond, M. G., Hartl, Franti\vsek,, Hogarth, G. (2022). Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe 4 S 4 surrogates.. Other.
Rajbangshi, S., Ghosh, S., Hogarth, G., Nesterov, V. V., Nesterov, V. N., Richmond, M. G., Kabir, S. E., Roesky, H. W. (2022). Stereochemical control of the diphosphine and alkyne ligands in triruthenium clusters: The effect of reversible CO loss/addition on the ligand distribution in [Ru3 ($\mu$3, $\eta$2-PhCCPh)$\{$$\mu$-Ph2PCH (Me) PPh2$\}$(CO) 7, 8]. Journal of Organometallic Chemistry. 968, 122337. Elsevier.
Hand, A. T., Lamb, A. C., Richmond, M. G., Wang, X., Steren, C. A., Xue, Z. (2022). Syntheses of Group 5 Amide Amidinates and Their Reactions with Water: Different Reactivities of Nb (V) and Ta (V) Complexes. Inorganic Chemistry. American Chemical Society.
Yang, L., Nesterov, V. N., Richmond, M. G. (2021). Bimodal substitution behavior in the reaction of N, N’-diisopropylformamidine with [Os3 (CO) 10 (NCMe) 2]: Kinetics and molecular structures of the formamidinate-substituted clusters HOs3 (CO) 9 [$\mu$-C (O) NPriC (H) NPri], HOs3 (CO) 10 [$\mu$-NPriC (H) NPri], and HOs3 (CO) 9 [$\mu$3-NPriC (H) NPri]. Journal of Organometallic Chemistry. 936, 121709. Elsevier.
Al Mamun, M. A., Rajbangshi, S., Ghosh, S., Richmond, M. G., Kabir, S. E. (2021). Ligand coordination in [Re2 (CO) 9 (NCMe)] and [H3Re3 (CO) 11 (NCMe)] by triphenylantimony: Reactivity studies and Sb--Ph bond cleavage to give new antimony-containing di-and trirhenium complexes. Journal of Organometallic Chemistry. 953, 122034. Elsevier.
Hossain, M. K., Schachner, J\"org A,, Haukka, M., Richmond, M. G., M\"osch-Zanetti, Nadia C,, Lehtonen, A., Nordlander, E. (2021). Oxygen Atom Transfer Catalysis by Dioxidomolybdenum (VI) Complexes of Pyridyl Aminophenolate Ligands. Polyhedron. 115234. Pergamon.
Rahaman, A., Lisensky, G. C., Haukka, M., Tocher, D. A., Richmond, M. G., Colbran, S. B., Nordlander, E. (2021). Proton reduction by phosphinidene-capped triiron clusters. Journal of Organometallic Chemistry. 943, 121816. Elsevier.
Joy, M. T., Bhoumik, N. C., Ghosh, S., Richmond, M. G., Kabir, S. E. (2020). A new synthetic route for the preparation of [Os 3 (CO) 10 ($\mu$-OH)($\mu$-H)] and its reaction with bis (diphenylphosphino) methane (dppm): syntheses and X-ray structures of two isomers of [Os 3 (CO) 8 ($\mu$-OH)($\mu$-H)($\mu$-dppm)] and [Os 3 (CO) 7 ($\mu$ 3-CO)($\mu$ 3-O)($\mu$-dppm)]. RSC Advances. 10(73), 44699--44711. Royal Society of Chemistry.
Abdel-Magied, A. F., Theibich, Y., Singh, A. K., Rahaman, A., Doverbratt, I., Raha, A. K., Haukka, M., Richmond, M. G., Nordlander, E. (2020). Asymmetric hydrogenation of an $\alpha$-unsaturated carboxylic acid catalyzed by intact chiral transition metal carbonyl clusters--diastereomeric control of enantioselectivity. Dalton Transactions. 49(14), 4244--4256. Royal Society of Chemistry.
Hossain, M. K., K\"ohntopp, Anja,, Haukka, M., Richmond, M. G., Lehtonen, A., Nordlander, E. (2020). Cis-and trans molybdenum oxo complexes of a prochiral tetradentate aminophenolate ligand: Synthesis, characterization and oxotransfer activity. Polyhedron. 178, 114312. Pergamon.
Rahaman, A., Lisensky, G. C., Browder-Long, J., Hrovat, D. A., Richmond, M. G., Nordlander, E., Hogarth, G. (2020). Electrocatalytic proton-reduction behaviour of telluride-capped triiron clusters: tuning of overpotentials and stabilization of redox states relative to lighter chalcogenide analogues. Dalton Transactions. Royal Society of Chemistry.
Nordlander, E., Li, C., Rahaman, A., Lin, W., Mourad, H., Meng, J., Honarfar, A., Abdellah, M., Guo, M., Richmond, M. G., others, (2020). Electron transfer mediated by iron carbonyl clusters enhance light-driven hydrogen evolution in water by quantum dots. ChemSusChem.
Bhoumik, N. C., Saha, T. K., Ghosh, S., Nesterov, V. N., Richmond, M. G., Kabir, S. E. (2020). Facile Os-Os bond cleavage in the reactions of [Os3 (CO) 10 (NCMe) 2] and [Os3 (CO) 10 ($\mu$-H) 2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand (s). Journal of Organometallic Chemistry. 911, 121133. Elsevier.
Mia, M. J., Reza, M. S., Bhoumik, N. C., Ghosh, S., Nesterov, V. N., Richmond, M. G., Kabir, S. E. (2020). Reactions of [Ru3 (CO) 12] with thiosaccharin: Synthesis and structure of di-, tri-, tetra-and penta-ruthenium complexes containing a thiosaccharinate ligand (s). Journal of Organometallic Chemistry. 906, 121048. Elsevier.
Joy, M. T., Hossain, M. E., Ghosh, S., Tocher, D. A., Richmond, M. G., Kabir, S. E., others, (2020). Reactions of triosmium and triruthenium clusters with 2-ethynylpyridine: new modes for alkyne C--C bond coupling and C--H bond activation. RSC Advances. 10(51), 30671--30682. Royal Society of Chemistry.
Bhoumik, N. C., Joy, M. T., Ghosh, S., Richmond, M. G., Kabir, S. E. (2020). Thermolysis of [HOs3 (CO) 8 $\{$$\mu$3-Ph2PCH2P (Ph) C6H4$\}$]: New Os2 and Os3 cluster products based on multiple C--H bond activation of the bis (diphenylphosphino) methane ligand. Inorganica Chimica Acta. 119733. Elsevier.
Pinky, T., Rahman, M. M., Ghosh, S., Azam, K. A., Mia, M. J., Alam, M. M., Tocher, D. A., Richmond, M. G., Kabir, S. E. (2019). Activation of thiosaccharin at a polynuclear osmium cluster. Journal of Organometallic Chemistry. 880, 223--231. Elsevier.
Rahaman, A., Ghosh, S., Basak-Modi, S., Abdel-Magied, A. F., Kabir, S. E., Haukka, M., Richmond, M. G., Lisensky, G. C., Nordlander, E., Hogarth, G. (2019). Chalcogenide-capped triiron clusters [Fe3 (CO) 9 ($\mu$3-E) 2],[Fe3 (CO) 7 ($\mu$3-CO)($\mu$3-E)($\mu$-dppm)] and [Fe3 (CO) 7 ($\mu$3-E) 2 ($\mu$-dppm)](E= S, Se) as proton-reduction catalysts. Journal of Organometallic Chemistry. 880, 213--222. Elsevier.
Ghosh, S., Rana, S., Kabir, S. E., Richmond, M. G., Hogarth, G. (2019). Highly efficient electrocatalytic proton-reduction by coordinatively and electronically unsaturated Fe (CO)($\kappa$2-dppn)($\kappa$2-tdt). Inorganica Chimica Acta. 486, 435--440. Elsevier.
Ghosh, S., Hollingsworth, N., Warren, M., Hrovat, D. A., Richmond, M. G., Hogarth, G. (2019). Hydrogenase biomimics containing redox-active ligands: Fe 2 (CO) 4 ($\mu$-edt)($\kappa$ 2-bpcd) with electron-acceptor 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) as a potential [Fe 4--S 4] H surrogate. Dalton Transactions. 48(18), 6051--6060. Royal Society of Chemistry.
Unwin, D. G., Ghosh, S., Ridley, F., Richmond, M. G., Holt, K. B., Hogarth, G. (2019). Models of the iron-only hydrogenase enzyme: structure, electrochemistry and catalytic activity of Fe 2 (CO) 3 ($\mu$-dithiolate)($\mu$, $\kappa$ 1, $\kappa$ 2-triphos). Dalton Transactions. 48(18), 6174--6190. Royal Society of Chemistry.
Hossain, M. M., Akter, N., Ghosh, S., Nesterov, V. N., Richmond, M. G., Hogarth, G., Kabir, S. E. (2019). New molecular architectures containing low-valent cluster centres with di-and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru 5 (CO) 15 ($\mu$ 5-C 4 H 2 N 2 CH [double bond, length as m-dash] CH)($\mu$-H) 2 and Ru 8 (CO) 24 ($\mu$ 7-C 4 H 2 N 2 CH [double bond, length as m-dash] C)($\mu$-H) 3. RSC Advances. 9(36), 21025--21030. Royal Society of Chemistry.
Mayberry, D. D., Nesterov, V. N., Richmond, M. G. (2019). Polyhedral Flexibility in the Sulfido-Capped Cluster H2Ru3 (CO) 9 ($\mu$3-S) on Reaction with 2-(Diphenylphosphino) thioanisole (PS) and Reversible Tripodal Rotation of the Chelated PS Ligand in H2Ru3 (CO) 7 ($\kappa$2-PS)($\mu$3-S). Organometallics. American Chemical Society.
Roy, P. S., Joy, M. T., Ghosh, S., Tocher, D. A., Nesterov, V. N., Richmond, M. G., Kabir, S. E. (2019). Reactions of [Os3 (CO) 10 ($\mu$-dppm)] and [HOs3 (CO) 8 $\{$$\mu$3-Ph2PCH2P (Ph) C6H4$\}$] with Bu3GeH: Ge--H and Ge--C bond cleavage at triosmium centers. Journal of Organometallic Chemistry. 898, 120862. Elsevier.
Abedin, S. T., Haque, M. R., Ghosh, S., Tocher, D. A., Richmond, M. G., Kabir, S. E., others, (2019). Reactivity of [Mo (CO) 3 (NCMe) 3] towards pyrimidine-2-thiol (pymSH) and thiophenol (PhSH) in the presence of phosphine auxiliaries: Synthesis of mono-and dinuclear complexes bearing $\kappa$2 and $\mu$, $\kappa$2-pymS coordination motifs. Polyhedron. 164, 55--63. Pergamon.
Mukherjee, A., Hrovat, D. A., Richmond, M. G., Bhattacharya, S. (2018). A new diphosphine-carbonyl complex of ruthenium: an efficient precursor for C--C and C--N bond coupling catalysis. Dalton Transactions. 47(30), 10264--10272. Royal Society of Chemistry.
Moni, M. R., Ghosh, S., Mobin, S. M., Tocher, D. A., Hogarth, G., Richmond, M. G., Kabir, S. E. (2018). Diphosphine-induced thiolate-bridge scission of [Re (CO) 3 ($\mu$, $\kappa$2-S, N-thpymS)] 2 (thpymS= 1, 4, 5, 6-tetrahydropyrimidine-2-thiolate): Structural and computational studies of configurational isomers of [Re (CO) 3 ($\kappa$2-S, N-thpymS)] 2 ($\mu$, $\kappa$1, $\kappa$1-dppe). Journal of Organometallic Chemistry. 871, 167--177. Elsevier.
Ghosh, S., Basak-Modi, S., Richmond, M. G., Nordlander, E., Hogarth, G. (2018). Electrocatalytic proton reduction by thiolate-capped triiron clusters [Fe3 (CO) 9 ($\mu$3-SR)($\mu$-H)](R= iPr, tBu). Inorganica Chimica Acta. 480, 47--53. Elsevier.
Begum, S. A., Chowdhury, M. A., Ghosh, S., Tocher, D. A., Richmond, M. G., Yang, L., Hardcastle, K., Rosenberg, E., Kabir, S. E. (2018). Experimental and computational preference for phosphine regioselectivity and stereoselective tripodal rotation in HOs 3 (CO) 8 (PPh 3) 2 ($\mu$-1, 2-N, C-$\eta$ 1, $\kappa$ 1-C 7 H 4 NS). RSC Advances. 8(57), 32672--32683. Royal Society of Chemistry.
Hogarth, G., Ghosh, S., Hollingsworth, N., Richmond, M. G., Kabir, S., Rana, S. (2018). Hydrogenase biomimetics with redox-active ligands: Synthesis, structure and electrocatalytic studies on Fe2 (CO) 4 (K2-dppn)($\mu$-edt)(edt= ethanedithiolate; dppn= 1, 8-bis (diphenylphosphino) naphthalene). Preprints. org.
Haque, M. R., Ghosh, S., Rahman, M. M., Siddiquee, T. A., Nesterov, V. N., Richmond, M. G., Hogarth, G., Kabir, S. E. (2018). Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl ligands: synthesis, structure, and electrochemistry of Mo 2 (O)(CO) 2 ($\mu$-$\kappa$ 2-S (CH 2) n S) 2 ($\kappa$ 2-diphosphine). Dalton Transactions. 47(30), 10102--10112. Royal Society of Chemistry.
Rahaman, A., Lisensky, G. C., Tocher, D. A., Richmond, M. G., Hogarth, G., Nordlander, E. (2018). Synthesis and molecular structures of the 52-electron triiron telluride clusters [Fe3 (CO) 8 ($\mu$3-Te) 2 ($\kappa$2-diphosphine)]-Electrochemical properties and activity as proton reduction catalysts. Journal of Organometallic Chemistry. 867, 381--390. Elsevier.
Lin, C., Nesterov, V. N., Richmond, M. G. (2018). Synthesis and redox properties of fac-BrRe (CO) 3 [1, 2-(PPh2) 2-closo-1, 2-C2B10H10]: The first structurally characterized rhenium carbonyl containing a carboranyl-based diphosphine ligand. Journal of Molecular Structure. 1156, 397--402. Elsevier.
Atim, S., Yang, L., Nesterov, V., Wang, X., Richmond, M. G. (2018). Synthesis of the labile rhenuim (I) complexes fac-Re (CO) 3 (L)[$\kappa$ 2-O, O-FcC (O) CHC (O) Me](where Fc= ferrocenyl; L= THF, H 2 O, alkyne) and alkyne addition to the diketonate ligand. Journal of Organometallic Chemistry. Elsevier.
Nesterov, V. V., Zakharov, L. N., Nesterov, V. N., Calderon, J. G., Longo, A., Zaman, K., Choudhury, F. K., Farrell, W., Shulaev, V., Richmond, M. G. (2017). 5, 7-Dihydroxy-2-(4-hydroxyphenyl) chroman-4-one (naringenin): X-ray diffraction structures of the naringenin enantiomers and DFT evaluation of the preferred ground-state structures and thermodynamics for racemization. Journal of Molecular Structure. 1130, 994–1000. Elsevier.
Uddin, K. M., Chowdhury, M. A., Hossain, M. K., Ghosh, S., Tocher, D. A., Richmond, M. G., Kabir, S. E. (2017). Alkyne activation and polyhedral reorganization in benzothiazolate-capped osmium clusters on reaction with diethyl acetylenedicarboxylate (DEAD) and ethyl propiolate. Dalton Transactions. 46(39), 13597--13609. Royal Society of Chemistry.
Mayberry, D. D., Nesterov, V. N., Richmond, M. G. (2017). Ambidentate ligand reactivity with the rhenium (I) compounds [BrRe (CO) 4] 2 and cis-BrRe (CO) 4L: A kinetic and mechanistic study. European Journal of Inorganic Chemistry.
Mitra, M., Nimir, H., Hrovat, D. A., Shteinman, A. A., Richmond, M. G., Costas, M., Nordlander, E. (2017). Catalytic CH oxidations by nonheme mononuclear Fe (II) complexes of two pentadentate ligands: Evidence for an Fe (IV) oxo intermediate. Journal of Molecular Catalysis A: Chemical. 426, 350–356. Elsevier.
Nyamwihura, R., Yang, L., Nesterov, V. N., Richmond, M. G. (2017). Diphosphine-bridged digold (I) compounds: Structural and computational studies on the aurophilic interaction in Au 2 Cl 2 ($\mu$-bpcd) and Au 2 Cl 2 ($\mu$-bmi). Journal of Molecular Structure. 1129, 188--194. Elsevier.
Khan, M. M., Ghosh, S., Hogarth, G., Tocher, D. A., Richmond, M. G., Kabir, S. E., Roesky, H. W. (2017). Mixed main group transition metal clusters: Reactions of [Ru 3 (CO) 10 ($\mu$-dppm)] with Ph 3 SnH. Journal of Organometallic Chemistry. 840, 47--55. Elsevier.
Khan, M. M., Alam, M., Ghosh, S., Rahaman, A., Tocher, D. A., Richmond, M. G., Kabir, S. E., Roesky, H. W. (2017). Reactions of Ru 3 (CO) 10 ($\mu$-dppm) with Ph 3 GeH: Ge--H and Ge--C bond cleavage in Ph 3 GeH at triruthenium clusters. Journal of Organometallic Chemistry. 843, 75--86. Elsevier.
Begum, S. A., Chowdhury, M. A., Ghosh, S., Tocher, D. A., Richmond, M. G., Rosenberg, E., Kabir, S. E. (2017). Reactions of the face-capped benzothiazolate-substituted clusters Os 3 (CO) 9 ($\mu$ 3, $\eta$ 2-C 7 H 3 NSR)($\mu$-H)(R= H, Me) with PPh 3: Kinetic formation of Os 3 (CO) 9 (PPh 3)($\mu$, $\eta$ 2-C 7 H 3 NSR)($\mu$-H) and thermally induced ligand isomerization. Journal of Organometallic Chemistry. 849, 337--349. Elsevier.
Chowdhury, M. A., Haque, M. R., Ghosh, S., Mobin, S. M., Tocher, D. A., Hogarth, G., Richmond, M. G., Kabir, S. E., Roesky, H. W. (2017). Reversible CH bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 ($\mu$-dppm)($\mu$-H) 2 and Os 3 (CO) 8 ($\mu$-dppf)($\mu$-H) 2 with activated alkynes. Journal of Organometallic Chemistry. 836, 68--80. Elsevier.
Hossain, M., Haukka, M., Sillanp\"a\"a, R,, Hrovat, D. A., Richmond, M. G., Nordlander, E., Lehtonen, A. (2017). Syntheses and catalytic oxotransfer activities of oxo molybdenum (vi) complexes of a new aminoalcohol phenolate ligand. Dalton Transactions. 46(21), 7051--7060. Royal Society of Chemistry.
Jung, J. Y., Marolf, D. M., Yoon, S. H., Powell, G. L., Yang, L., Nesterov, V. N., Richmond, M. G. (2017). The reaction of Os 3 (CO) 12 with triphos $\{$MeC (CH 2 PPh 2) 3$\}$: A case of multiple CP and CH bond activations. Journal of Organometallic Chemistry. 849, 125--129. Elsevier.
Ghosh, S., Sanchez, B. E., Richards, I., Haque, M. N., Holt, K. B., Richmond, M. G., Hogarth, G. (2016). Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe 2 (CO) 4 ($\mu$-H)$\{$$\kappa$ 2-Ph 2 PC (Me 2) PPh 2$\}$($\mu$-pdt)]+ as a proton-reduction catalyst. Journal of Organometallic Chemistry. 812, 247--258. Elsevier.
Ghosh, S., Rahaman, A., Holt, K. B., Nordlander, E., Richmond, M. G., Kabir, S. E., Hogarth, G. (2016). Hydrogenase biomimetics with redox-active ligands: Electrocatalytic proton reduction by [Fe 2 (CO) 4 ($\kappa$ 2-diamine)($\mu$-edt)](diamine= 2, 2′-bipy, 1, 10-phen). Polyhedron. 116, 127--135. Elsevier.
Chowdhury, M. A., Rahman, M. S., Islam, M. R., Rajbangshi, S., Ghosh, S., Hogarth, G., Tocher, D. A., Yang, L., Richmond, M. G., Kabir, S. E. (2016). Iron carbonyl complexes bearing phenazine and acridine ligands: X-ray structures of Fe (CO) 3 ($\eta$ 4-C 12 H 8 N 2), Fe (CO) 2 $\{$P (OMe) 3$\}$($\eta$ 4-C 12 H 8 N 2), Fe (CO) 2 (PPh 3)($\eta$ 4-C 13 H 9 N), and Fe (CO) 2 ($\kappa$ 1-dppm)($\eta$ 4-C 12 H 8 N 2). Journal of Organometallic Chemistry. 805, 34--41. Elsevier.
Shim, E., Leong, W., Li, Y., Richmond, M. (2016). Isomerization of the osmium–tellurium cluster Os 3 ($μ$-TeR) 2 (CO) 10: a kinetic and computational study!!!. Dalton Transactions. 45(16), 7158–7162. Royal Society of Chemistry.
Jung, J. Y., Kempe, D. K., Yoon, S. H., Gwini, N., Fikes, A. G., Marolf, D. M., Parker, M. L., Johnstone, J. E., Powell, G. L., Yang, L., others, (2016). Microwave-induced dppm ligand substitution in triosmium clusters: Structural and DFT evaluation of Os 3 clusters containing multiply activated dppm ligands through cyclometalation, ortho metalation, and P C bond cleavage. Journal of Organometallic Chemistry. 813, 15–25. Elsevier.
Begum, S. A., Chowdhury, M. A., Ghosh, S., Tocher, D. A., Richmond, M. G., Rosenberg, E., Kabir, S. E. (2016). Reactions of the face-capped benzothiazolate-substituted clusters Os 3 (CO) 9 ($μ$ 3, $η$ 2-C 7 H 3 NSR)($μ$-H)(R= H, Me) with PPh 3: Kinetic formation of Os 3 (CO) 9 (PPh 3)($μ$, $η$ 2-C 7 H 3 NSR)($μ$-H) and thermally induced ligand isomerization!!!. Journal of Organometallic Chemistry. Elsevier.
Uddin, M. M., Begum, N., Ghosh, S., Sarker, J. C., Tocher, D. A., Hogarth, G., Richmond, M. G., Nordlander, E., Kabir, S. E. (2016). Thermal transformations of tris (2-thienyl) phosphine (PTh 3) at low-valent ruthenium cluster centers: Part I. Carbon--hydrogen, carbon--phosphorus and carbon--sulfur bond activation yielding Ru 3 (CO) 8 L $\{$$\mu$-Th 2 P (C 4 H 2 S)$\}$($\mu$-H)(L= CO, PTh 3), Ru 3 (CO) 7 ($\mu$-PTh 2) 2 ($\mu$ 3-$\eta$ 2-C 4 H 2 S), Ru 4 (CO) 9 ($\mu$-CO) 2 ($\mu$ 4-$\eta$ 2-C 4 H 2 S)($\mu$ 4-PTh) and Ru 5 (CO) 11 ($\mu$-PTh 2)($\mu$ 4-$\eta$ 4-C 4 H 3)($\mu$ 4-S). Journal of Organometallic Chemistry. 812, 197--206. Elsevier.
Ghosh, S., Holt, K. B., Kabir, S. E., Richmond, M. G., Hogarth, G. (2015). Electrocatalytic proton reduction catalysed by the low-valent tetrairon-oxo cluster [Fe 4 (CO) 10 ($κ$ 2-dppn)($μ$ 4-O)] 2-[dppn= 1, 1′-bis (diphenylphosphino) naphthalene]!!!. Dalton Transactions. 44(11), 5160–5169. Royal Society of Chemistry.
Mitra, M., Nimir, H., Demeshko, S., Bhat, S. S., Malinkin, S. O., Haukka, M., Lloret-Fillol, J., Lisensky, G. C., Meyer, F., Shteinman, A. A., others, (2015). Nonheme Fe (IV) oxo complexes of two new pentadentate ligands and their hydrogen-atom and oxygen-atom transfer reactions. Inorganic Chemistry. 54(15), 7152--7164. American Chemical Society.
Dutta, J., Richmond, M. G., Bhattacharya, S. (2015). Palladium (0)-mediated C–H bond activation of N-(naphthyl) salicylaldimine and related ligands: utilization of the resulting organopalladium complexes in catalytic C–C and C–N coupling reactions. Dalton Transactions. 44(30), 13615–13632. Royal Society of Chemistry.
Chowdhury, M. A., Rajbangshi, S., Rahaman, A., Yang, L., Nesterov, V. N., Richmond, M. G., Mobin, S. M., Kabir, S. E. (2015). Phenazine-substituted polynuclear osmium clusters: Synthesis and DFT evaluation of the C-metalated derivatives Os 3 (CO) 9 ($\mu$ 3, $\eta$ 2-C 12 H 7 N 2)($\mu$-H) and Os 3 (CO) 9 ($\mu$ 3, $\eta$ 2-C 12 H 6 N 2)($\mu$-H) 2. Journal of Organometallic Chemistry. 779, 21--29. Elsevier.
Yang, L., Nesterov, V. N., Richmond, M. G. (2015). Reaction of ethyl (2Z)-cyano-6-methoxyquinolin-2 (1H)-ylidene-ethanoate (L) with rhenium carbonyls: Structural and computational studies on the rhenium (I) compound cis-BrRe (CO) 4 L. Polyhedron. 94, 83–89. Elsevier.
Chowdhury, M. A., Rajbangshi, S., Karim, M., Ghosh, S., Kabir, S. E., Siddiquee, T. A., Nesterov, V. N., Richmond, M. G. (2015). Reactivity of [CpMo (CO) 2] 2 towards heterocyclic thiols: Synthesis, structure, and bonding in the sulfido-ligated cluster Cp 3 Mo 3 ($μ$-CO) 2 ($μ$-$κ$ 2-C 7 H 4 NS)($μ$-S)($μ$ 3-S)!!!. Inorganica Chimica Acta. 434, 97–103. Elsevier.
Hunter, S. C., Chen, S., Steren, C. A., Richmond, M. G., Xue, Z. (2015). Syntheses and Characterization of Tantalum Alkyl Imides and Amide Imides. DFT Studies of Unusual $\alpha$-SiMe3 Abstraction by an Amide Ligand. Organometallics. 34(24), 5687--5696. ACS Publications.
Yang, L., Nesterov, V. N., Wang, X., Richmond, M. G. (2015). Synthesis of the Stereoisomeric Clusters 1, 2-Os 3 (CO) 10 (trans-dpmn) and 1, 2-Os 3 (CO) 10 (cis-dpmn)[where dpmn= 2, 3-bis (diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1, 2-Os 3 (CO) 10 (dpmn) and Isomer-Dependent Diphosphine Ligand Activation. Journal of Cluster Science. 26(1), 93--109. Springer US.
Haque, M. R., Ghosh, S., Hogarth, G., Richmond, M. G., Kabir, S. E. (2015). Synthesis, structure and bonding of new mono-and dinuclear molybdenum complexes containing pyridine-2-thiolate (pyS) and different P-donors. Inorganica Chimica Acta. 434, 150–157. Elsevier.
Raha, A. K., Uddin, M. N., Ghosh, S., Miah, A. R., Richmond, M. G., Tocher, D. A., Nordlander, E., Hogarth, G., Kabir, S. E. (2014). A comparative study of the reactivity of the lightly stabilized cluster [Os 3 (CO) 8 $\{$$\mu$ 3-Ph 2 PCH 2 P (Ph) C 6 H 4$\}$($\mu$-H)] towards tri (2-thienyl)-, tri (2-furyl)-and triphenyl-phosphine. Journal of Organometallic Chemistry. 751, 399--411. Elsevier.
Sarker, J. C., Raha, A. K., Ghosh, S., Hogarth, G., Kabir, S. E., Richmond, M. G. (2014). Backbone modified small bite-angle diphosphines: Synthesis, structure, and DFT evaluation of the thermal activation products based on Os 3 (CO) 10 $\{$$\mu$-Ph 2 PC (Me) 2 PPh 2$\}$. Journal of Organometallic Chemistry. 750, 49--58. Elsevier.
Sarker, J. C., Uddin, K. M., Rahman, M. S., Ghosh, S., Siddiquee, T. A., Tocher, D. A., Richmond, M. G., Hogarth, G., Kabir, S. E. (2014). Bimetallic osmium-tin complexes: Stannylene and hydrostannylene clusters upon addition of Ph 3 SnH to unsaturated triosmium clusters [($\mu$-H) 2 Os 3 (CO) 8 ($\mu$-diphosphine)](diphosphine= dppm, dppf). Inorganica Chimica Acta. 409, 320--329. Elsevier.
Rahaman, A., Ghosh, S., Unwin, D. G., Basak-Modi, S., Holt, K. B., Kabir, S. E., Nordlander, E., Richmond, M. G., Hogarth, G. (2014). Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe3 (CO) 7 ($\mu$-edt) 2] and Phosphine Derivatives [Fe3 (CO) 7--x (PPh3) x ($\mu$-edt) 2](x= 1, 2) and [Fe3 (CO) 5 ($\kappa$2-diphosphine)($\mu$-edt) 2] as Proton Reduction Catalysts. Organometallics. 33(6), 1356--1366. American Chemical Society.
Dutta, J., Richmond, M. G., Bhattacharya, S. (2014). Cycloruthenation of N-(Naphthyl) salicylaldimine and Related Ligands: Utilization of the Ru--C Bond in Catalytic Transfer Hydrogenation. European Journal of Inorganic Chemistry. 2014(27), 4600--4610. Wiley Online Library.
Richmond, M. G., Xue, Z. (2014). DFT examination of rare $\alpha$-SiMe 3 abstraction in Ta (NMe 2) 4 [N (SiMe 3) 2]: formation of the imide compound Ta ([double bond, length as m-dash] NSiMe 3)(NMe 2) 3 and its trapping to give guanidinate imides. Dalton Transactions. 43(32), 12390--12395. Royal Society of Chemistry.
Abdel-Magied, A. F., Singh, A. K., Haukka, M., Richmond, M. G., Nordlander, E. (2014). Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis. Chemical Communications. 50(57), 7705--7708. Royal Society of Chemistry.
Hossain, M. J., Rajbangshi, S., Khan, M. M., Ghosh, S., Hogarth, G., Rosenberg, E., Hardcastle, K. I., Richmond, M. G., Kabir, S. E. (2014). Experimental and computational studies on the reaction of silanes with the diphosphine-bridged triruthenium clusters Ru 3 (CO) 10 ($\mu$-dppf), Ru 3 (CO) 10 ($\mu$-dppm) and Ru 3 (CO) 9 $\{$$\mu$ 3-PPhCH 2 PPh (C 6 H 4)$\}$. Journal of Organometallic Chemistry. 767, 185--195. Elsevier.
Paul, P., Richmond, M. G., Bhattacharya, S. (2014). Iridium-mediated N--H and methyl C--H bond activations in N-(2′, 6′-dimethylphenyl) pyrrole-2-aldimine. Synthesis, characterization and catalytic applications. Journal of Organometallic Chemistry. 751, 760--768. Elsevier.
Huang, S., Nesterov, V. N., Richmond, M. G. (2014). New azido-substituted tantalum compounds: syntheses and DFT examination of nitrogen-rich mono-, di-, and trinuclear tantalum (V) compounds. Dalton Transactions. 43(9), 3453--3461. Royal Society of Chemistry.
Celaje, J. A., Pennington-Boggio, M. K., Flaig, R. W., Richmond, M. G., Williams, T. J. (2014). Synthesis and Characterization of Dimethylbis (2-pyridyl) borate Nickel (II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel (II). Organometallics. 33(8), 2019--2026. American Chemical Society.
Hossain, M. K., Rajbangshi, S., Rahaman, A., Chowdhury, M. A., Siddiquee, T. A., Ghosh, S., Richmond, M. G., Nordlander, E., Hogarth, G., Kabir, S. E. (2014). Synthesis of [Ru 3 (CO) 9 ($\mu$-dppf)$\{$P (C 4 H 3 E) 3$\}$](E= O, S) and thermally induced cyclometalation to form [($\mu$-H) Ru 3 (CO) 7 ($\mu$-dppf)$\{$$\mu$ 3-(C 4 H 3 E) 2 P (C 4 H 2 E)$\}$](dppf= 1, 1′-bis (diphenylphosphino) ferrocene). Journal of Organometallic Chemistry. 760, 231--239. Elsevier.
Pennington-Boggio, M. K., Conley, B. L., Richmond, M. G., Williams, T. J. (2014). Synthesis, structure, and conformational dynamics of rhodium and iridium complexes of dimethylbis (2-pyridyl) borate. Polyhedron. 84, 24--31. Elsevier.
Paul, P., Seth, D. K., Richmond, M. G., Bhattacharya, S. (2014). Unusual chemical transformations of acetone thiosemicarbazone mediated by ruthenium: C--H bond activation, thiolation, and C--N bond cleavage. RSC Advances. 4(3), 1432--1440. Royal Society of Chemistry.
Lin, C., Nesterov, V. N., Richmond, M. G. (2013). 2-[(Diphenylphosphino) methyl]-6-methylpyridine (PN) coordination chemistry at triosmium clusters: Regiospecific ligand activation and DFT evaluation of the isomeric Os 3 (CO) 10 (PN) clusters. Journal of Organometallic Chemistry. 744, 24--34. Elsevier.
Al-Jibori, S. A., Dayaaf, N. A., Mohammed, M. Y., Merzweiler, K., Wagner, C., Hogarth, G., Richmond, M. G. (2013). cis--trans Isomerism at Square-Planar MN 2 S 2 Centers (M= Pd, Pt): Crystal Structures of N-Phenyl-N-(2-thiazoyl) thiourea Complexes trans-Pd (S 2 N 3 C 10 H 8) 2 and cis-Pt (S 2 N 3 C 10 H 8) 2 and Density Functional Calculations. Journal of Chemical Crystallography. 43(7), 365--372. Springer US.
Ghosh, S., Hogarth, G., Hollingsworth, N., Holt, K. B., Richards, I., Richmond, M. G., Sanchez, B. E., Unwin, D. (2013). Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe 2 (CO) 4 $\{$Ph 2 PN (R) PPh 2$\}$($\mu$-pdt) as proton-reduction catalysts. Dalton Transactions. 42(19), 6775--6792. Royal Society of Chemistry.
Ahmad, M. F., Sarker, J. C., Azam, K. A., Kabir, S. E., Ghosh, S., Hogarth, G., Siddiquee, T. A., Richmond, M. G. (2013). Re 2 (CO) 6 ($\mu$-thpymS) 2 (thpymSH= pyrimidine-2-thiol) as a versatile precursor to mono-and polynuclear complexes: X-ray crystal structures of fac-Re (CO) 3 (PPh 3)($\kappa$ 2-thpymS) and two isomers of ReRu 3 (CO) 13 ($\mu$ 3-thpymS). Journal of Organometallic Chemistry. 728, 30--37. Elsevier.
Lin, C., Pan, H., Nesterov, V. N., Richmond, M. G. (2013). Reaction of 4-(2, 2-dimethylhydrazino) dimethylhydrazone-3 (Z)-penten-2-one with BrRe (CO) 5 and fac-BrRe (CO) 3 (THF) 2: Synthesis, structural characterization, and DFT examination of the $\beta$-diketimine-substituted compound fac-BrRe (CO) 3 [(Me 2 NNCMe) 2 CH 2]. Journal of Organometallic Chemistry. 748, 56--62. Elsevier.
Nesterov, V. V., Yang, L., Nesterov, V. N., Richmond, M. G. (2013). Structural and computational features of four highly polar quinolin-2 (1H)-ylidene derivatives: Equilibrium preference for enaminothione, enamine, and enaminone tautomeric structures. Journal of Molecular Structure. 1054, 262--270. Elsevier.
Persson, R., Stchedroff, M. J., Gobetto, R., Carrano, C. J., Richmond, M. G., Monari, M., Nordlander, E. (2013). Synthesis, characterization, and dynamic behaviour of triosmium clusters containing the tridentate ligand $\{$Ph2PCH2CH2$\}$ 2S (PSP). European Journal of Inorganic Chemistry. 2013(13), 2447--2459. Wiley Online Library.
Ghosh, S., Hogarth, G., Kabir, S. E., Raha, A. K., Richmond, M. G., Sarker, J. C. (2012). Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os 3 (CO) 10 $\{$$\mu$-Ph 2 PCH (Me) PPh 2$\}$. Journal of Cluster Science. 23(3), 781--798. Springer US.
Yang, L., Nesterov, V. N., Wang, X., Richmond, M. G. (2012). CO Substitution in HOs 3 (CO) 10 ($\mu$-SC 6 H 4 Me-4) by the Diphosphine 4, 5-Bis (diphenylphosphino)-4-cyclopentadiene-1, 3-dione (bpcd): Structural and DFT Evaluation of the Isomeric Clusters HOs 3 (CO) 8 (bpcd)($\mu$-SC 6 H 4 Me-4). Journal of Cluster Science. 23(3), 685--702. Springer US.
Hrovat, D. A., Nordlander, E., Richmond, M. G. (2012). DFT investigation of the mechanism of phosphine-thioether isomerization in the triosmium cluster Os3 (CO) 10 (Ph2PCH2CH2SMe): Migratory preference for the formation of an edge-bridged thioether versus a phosphine moiety. Organometallics. 31(18), 6608--6613. American Chemical Society.
Hunt, S. W., Nesterov, V., Richmond, M. G. (2012). Ligand substitution in 1, 2-Os₃ (CO) ₁₀ (MeCN) ₂ by the diphosphine (PhO) ₂PN (Me) N (Me) P (OPh) ₂: X-ray diffraction structure of 1, 2-Os₃ (CO) ₁₀ [(PhO) ₂PN (Me) N (Me) P (OPh) ₂] and DFT investigation of the isomeric Os₃ (CO) ₁₀ [(PhO) ₂PN (Me) N (Me) P (OPh) ₂] clusters. Journal of Molecular Structure. Elsevier BV.
Huang, S., Wang, X., Richmond, M. G. (2012). Phosphinoborane-induced fragmentation of the unsaturated hydride H 2 Re 2 (CO) 8: X-ray structure of HRe (CO) 4 ($\kappa$ B, P-Ph 2 PCH 2 CH 2 BR 2)(where BR 2= 9-borabicyclo [3.3. 1] nonanyl) and DFT Evaluation of hydride versus CO coordination by the ancillary borane. Journal of Organometallic Chemistry. 700, 103--109. Elsevier.
Nesterov, V. V., Nesterov, V. N., Richmond, M. G. (2012). Structural characterization of cis-2, 6-(E, E)-bis (ferrocenylidene)-N-methyl-4-piperidone and DFT evaluation of alternative polymorphic modifications via ferrocene rotation. Polyhedron. 35(1), 124--129. Elsevier.
Huang, S., Nesterov, V. N., Richmond, M. G. (2012). Synthesis and Structural Characterization of the Pentanuclear Tantalum Cluster Ta5 ($\mu$5-N)($\mu$3-NiPr) 2 ($\mu$2-NiPr) 6 ($\eta$1-NiPr) 4 ($\eta$1-NHiPr) 2 from the Reaction of Ta (NMe2) 5 and iPrNH2: Unprecedented Formation of a Hinged-Butterfly Cluster Containing an Interstitial Nitride, Imido Groups, and Amido Groups. Journal of Chemical Crystallography. 42(9), 916--922. Springer US.
Huang, S., Wang, X., Nesterov, V., Hrovat, D. A., Hall, M. B., Richmond, M. G. (2011). Allyl Ligand Reactivity in Tantalum (V) Compounds: Experimental and Computational Evidence for Allyl Transfer to the Formamidinate Ligand in fac-Ta (NMe2) 3 ($\eta$1-allyl)[i PrNC (H) N i Pr] via a Metallo-Claisen Rearrangement. Organometallics. 30(21), 5832--5843. ACS Publications.
Zhang, X., Kandala, S., Yang, L., Watson, W. H., Wang, X., Hrovat, D. A., Borden, W. T., Richmond, M. G. (2011). Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phosphine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3 (CO) 10 (dppbz), 1, 1-Os3 (CO) 10 (dppbzF4), HOs3 (CO) 9 [$\mu$-1, 2-PhP (C6H4-$\eta$1) C6H4PPh2], and HOs3 (CO) 9 [$\mu$-1, 2-PhP (C6H4-$\eta$1) C6F4PPh2]. Organometallics. 30(5), 1253--1268. American Chemical Society.
Hunt, S. W., Yang, L., Wang, X., Richmond, M. G. (2011). New osmium cluster compounds containing the heterocyclic ligand 2, 3-bis-(diphenylphosphino) quinoxaline (dppq): Ligand isomerization and crystal structures of dppq, the isomeric clusters Os 3 (CO) 10 (dppq), and HOs 3 (CO) 9 [$\mu$-2, 3-PhP ($\eta$ 1-C 6 H 4)(Ph 2 P) quinoxaline]. Journal of Organometallic Chemistry. 696(7), 1432--1440. Elsevier.
Wang, X., Huang, S., Richmond, M. G. (2010). Chloride Metathesis and Dimethylamide Transfer in the Reaction of TaCl (NMe 2) 4 with ZnMe 2 and MeMgCl: Spectroscopic Studies and X-ray Diffraction Structures of TaCl (Me)(NMe 2) 3 and ZnCl 2 (NHMe 2) 2. Journal of Chemical Crystallography. 40(2), 173--178. Springer US.
Hammons, C., Wang, X., Nesterov, V., Richmond, M. G. (2010). Diphosphine-and CO-Induced Fragmentation of Chloride-bridged Dinuclear Complex and Cp* Ir ($\mu$-Cl) 3 Re (CO) 3 and Attempted Synthesis of Cp* Ir ($\mu$-Cl) 3 Mn (CO) 3: Spectroscopic Data and X-ray Diffraction Structures of the Pentamethylcyclopentadienyl Compounds [Cp* IrCl $\{$(Z)-Ph 2 PCH= CHPPh 2$\}$][Cl]\textperiodcentered 2CHCl 3 and Cp* Ir (CO) Cl 2. Journal of Chemical Crystallography. 40(5), 453--460. Springer US.
Kandala, S., Yang, L., Campana, C. F., Nesterov, V., Wang, X., Richmond, M. G. (2010). Isomerization of the diphosphine ligand 3, 4-bis (diphenylphosphino)-5-methoxy-2 (5H)-furanone (bmf) at a triosmium cluster and P--C bond cleavage in the unsaturated cluster 1, 1-Os 3 (CO) 9 (bmf): Synthesis and X-ray diffraction structures of the isomeric Os 3 (CO) 10 (bmf) clusters and HOs 3 (CO) 8 ($\mu$-C 6 H 4)[$\mu$-PhPC C (Ph 2 P) CH (OMe) OC (O)]. Polyhedron. 29(14), 2814--2821. Elsevier.
Kandala, S., Hammons, C., Watson, W. H., Wang, X., Richmond, M. G. (2010). Ligand substitution behavior of Ru6 ($\mu$6-C)(CO) 17 with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P--C bond cleavage in the cluster Ru6 ($\mu$6-C)(CO) 14 ($\mu$3-bpcd). Dalton Transactions. 39(6), 1620--1629. Royal Society of Chemistry.
Huang, S., Pilvi, T., Wang, X., Leskel\"a, Markku,, Richmond, M. G. (2010). New octahedral Ta (V) hydrazido-substituted compounds for atomic layer deposition: Syntheses, X-ray diffraction structures of TaCl (NMe 2) 3 [N (TMS) NMe 2] and Ta (NMe 2) 4 [N (TMS) NMe 2], and fluxional behavior of the amido and hydrazido ligands in solution. Polyhedron. 29(7), 1754--1759. Elsevier.
Hunt, S. W., Yang, L., Wang, X., Nesterov, V., Richmond, M. G. (2010). New Pt (II)(dithiolate) Compounds Possessing an Energetically Accessible Diphosphine-Based LUMO: Syntheses, Redox Properties, and Solid-State Structures of PtCl 2 (pbpcd), Pt (tdt)(pbpcd), and Pt (tdt)(bpcd). Journal of Inorganic and Organometallic Polymers and Materials. 20(3), 457--467. Springer US.
Huang, S., Keith, J. M., Hall, M. B., Richmond, M. G. (2010). Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3 (CO) 10 (dppm) to HOs3 (CO) 8 [$\mu$-PhP (C6H4-$\mu$2, $\eta$1) CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C- H and $\pi$-Aryl Intermediates at an Intact Triosmium Cluster. Organometallics. 29(18), 4041--4057. ACS Publications.
Atim, S., Wang, X., Richmond, M. G. (2010). Synthesis of the donor--acceptor ligand 2-(4-dimethylaminobenzylidene)-4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (dbpcd) and X-ray diffraction structure of the platinum (II) compound PtCl2 (dbpcd)\textperiodcentered 1.5 CH2Cl2. Inorganica Chimica Acta. 363(2), 418--423. Elsevier.
Hunt, S., Wang, X., Richmond, M. G. (2009). "Synthesis, Reactivity Investigation, and X-ray Diffraction Structures of New Platinum(II) Compounds Containing Redox-Active Diphosphine Ligands,". Journal of Molecular Structure.
Carrano, C. J., Wang, X., Poola, B., Powell, C. B., Richmond, M. G. (2009). $\alpha$-Diimine Ligand Coordination and C--H Bond Activation in the Reaction of Os 3 (CO) 10 (MeCN) 2 with 6-R-2, 2′-Bipyridine (where R= Et, Ph): X-ray Diffraction Structures of the Ortho-Metalated Hydride Clusters HOs 3 (CO) 9 (N 2 C 10 H 6-6-R). Journal of Chemical Crystallography. 39(11), 820--826. Springer US.
Huang, S., Watson, W. H., Carrano, C. J., Wang, X., Richmond, M. G. (2009). Directed Synthesis of the Triangular Mixed-Metal Cluster H2RhRe2Cp*(CO) 9: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of CO, Halogenated Solvents, and Thiols. Organometallics. 29(1), 61--75. ACS Publications.
Watson, W. H., Huang, S., Yang, L., Richmond, M. G. (2009). Ligand Substitution Chemistry of the Diphosphine Ligand endo, endo-2, 3-Bis (diphenylphosphinomethyl)-5-norbornene (dpmn): Syntheses and X-ray Diffraction Structures of PtCl 2 (dmn) and PtMe 2 (dpmn). Journal of Chemical Crystallography. 39(10), 740--746. Springer US.
Poola, B., Wang, X., Richmond, M. G. (2009). New rhenium (I) compounds containing the donor--acceptor diphosphine ligands 2-(ferrocenylidene)-4, 5-bis (diphenylphosphino) 4-cyclopenten-1, 3-dione (fbpcd) and 2-(3-ferrocenylprop-2-ynylidene)-4, 5-bis (diphenylphosphino) 4-cyclopenten-1, 3-dione (fpbpcd): Electrochemical behavior, MO properties, and X-ray diffraction structure of fac-BrRe (CO) 3 (fpbpcd). Polyhedron. 28(13), 2619--2624. Elsevier.
Wang, X., Hammons, C., Richmond, M. G. (2009). Preparation and reactivity of the heterobimetallic ReIr face-shared bioctahedral compounds Cp* Ir ($\mu$-Cl) 3 Re (CO) 3 and Cp* Ir ($\mu$-SC 6 H 4 Me-4) 3 Re (CO) 3: X-ray diffraction structures and redox behavior. Polyhedron. 28(11), 2294--2300. Elsevier.
Zhang, W., Watson, W. H., Richmond, M. G. (2009). Spectroscopic and X-ray Diffraction Data on Three Novel Trimetallic Clusters from Thermally Promoted Ligand Substitution in the Tetrahedrane Clusters MeCCo 2 MoCp (CO) 8 and PhCCo 2 Mo ($\eta$ 5-C 5 H 4 CHO)(CO) 8. Journal of Chemical Crystallography. 39(11), 812--819. Springer US.
Wang, X., Hunt, S. W., Richmond, M. G. (2009). Syntheses, Spectroscopic Data, and X-ray Diffraction Structures of the Heterometallic RuRe Face-shared Bioctahedral ($\eta$ 6-cymene) Ru ($\mu$-Cl) 3 Re (CO) 3 and MnRu 2 Edge-shared Trioctahedral [fac-ClRu (CO) 3] 2 ($\mu$-Cl) 4 Mn (H 2 O) 2 Complexes. Journal of Chemical Crystallography. 39(8), 589--594. Springer US.
Hunt, S. W., Wang, X., Richmond, M. G. (2009). Synthesis, reactivity investigation, and X-ray diffraction structures of new platinum (II) compounds containing redox-active diphosphine ligands. Journal of Molecular Structure. 919(1), 34--40. Elsevier.
Huang, S., Wang, X., Richmond, M. G. (2009). Transfer of Amide and 2-Methoxyethoxy Groups and Sodium Encapsulation in the Reaction of TaCl 3 [N (TMS) 2] 2 with Sodium Bis (2-methoxyethoxy) aluminum Hydride: X-ray Structure of [NaAl $\{$N (TMS) 2$\}$(OCH 2 CH 2 OMe) 3] 2. Journal of Chemical Crystallography. 39(6), 428--432. Springer US.
Bott, S., Shen, H., Huang, S., Richmond, M. G. (2008). "CO Substitution in HRu3(CO)10(μ-COMe) by the Unsaturated Diphosphine Ligand 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Synthesis and Reactivity Studies of the Face-capped Cluster Ru3(CO)7(μ3-COMe)[μ-P(Ph)C=C(PPh2)C(O)CH2C(O)],". Journal of Organometallic Chemistry.
Watson, W., Wu, G., Richmond, M. G. (2008). "Diphosphine Chelation and Bridging and Regiospecific Ortho Metalation in the Reaction of 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir4(CO)12: X‑ray Diffraction Structures of Ir4(CO)7(μ-CO)3(bpcd), Ir4(CO)5(μ-CO)3(bpcd)(μ-bpcd), and HIr4(CO)4(μ-CO)3(bpcd)[μ-PhP(C6H4)C=C(PPh2)C(O)CH2C(O)],". Journal of Organometallic Chemistry.
Zhang, W., Watson, W., Richmond, M. G. (2008). "Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2,3‑Bis(diphenylphosphino)maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo2MCp(CO)8 (where M = Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co2MCp(CO)6[μ-C=C(H)CH2C(PPh2)C(PPh2)C(O)OC(O)],". Journal of Chemical Crystallography.
Poola, B., Hunt, S., Wang, X., Richmond, M. G. (2008). "New Platinum Compounds Containing the Diphosphine Ligand 2-(Ferrocenylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Synthesis, Redox Behavior, and X-ray Diffraction Structures of PtCl2(fbpcd) and Pt(mnt)(fbpcd),". Polyhedron.
Carrano, C. J., Poola, B., Richmond, M. G. (2008). "Reaction of 6-Methyl-2,2'-bipyridine with 1,2-Os3(CO)10(MeCN)2: Syntheses, Reductive Elimination/Ligand Displacement Kinetics, and X-ray Diffraction Structures of the Isomeric Clusters HOs3(CO)9(μ2-N2C11H9) and H2Os3(CO)8(μ3-N2C11H8),". Organometallics Journals.
Zhang, W., Watson, W. H., Richmond, M. G. (2008). CO Substitution and Cluster-Ligand Reductive Coupling in the Reaction of 2, 3-Bis (diphenylphosphino) maleic Anhydride (bma) with the Mixed-metal Clusters PhCCo 2 MCp (CO) 8 (where M= Cr, W): Synthesis and X-ray Diffraction Structures of the Phosphido-bridged Clusters Co 2 MCp (CO) 5 [$\mu$ 2, $\eta$ 2, $\eta$ 1-C (Ph) C= C (PPh 2) C (O) OC (O)]($\mu$-PPh 2). Journal of Chemical Crystallography. 38(1), 9--15. Springer US.
Zhang, W., Watson, W., Richmond, M. G. (2008). CO Substitution and Cluster-Ligand Reductive Coupling in the Reaction of 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) with the Mixed-metal Clusters PhCCo2MCp(CO)8 (where M = Cr, W): Synthesis and X-ray Diffraction Structures of the Phosphido-bridged Clusters Co2MCp(CO)5[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ-PPh2),". Journal of Chemical Crystallography.
Bott, S. G., Shen, H., Huang, S., Richmond, M. G. (2008). CO substitution in HRu 3 (CO) 10 ($\mu$-COMe) by the unsaturated diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd): Synthesis and reactivity studies of the face-capped cluster Ru 3 (CO) 7 ($\mu$ 3-COMe)[$\mu$-P (Ph) C C (PPh 2) C (O) CH 2 C (O)]. Journal of Organometallic Chemistry. 693(13), 2327--2337. Elsevier.
Watson, W. H., Wu, G., Richmond, M. G. (2008). Diphosphine ligand chelation and bridging and regiospecific ortho metalation in the reaction of 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) with Ir 4 (CO) 12: X-ray diffraction structures of Ir 4 (CO) 7 ($\mu$-CO) 3 (bpcd), Ir 4 (CO) 5 ($\mu$-CO) 3 (bpcd)($\mu$-bpcd), and HIr 4 (CO) 4 ($\mu$-CO) 3 (bpcd)[$\mu$-PhP (C 6 H 4) C C (PPh 2) C (O) CH 2 C (O)]. Journal of Organometallic Chemistry. 693(8), 1439--1448. Elsevier.
Zhang, W., Watson, W. H., Richmond, M. G. (2008). Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2, 3-Bis (diphenylphosphino) maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo 2 MCp (CO) 8 (where M= Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co 2 MCp (CO) 6 [$\mu$--C= C (H) CH 2 C (PPh 2) C (PPh 2) C (O) OC (O)]. Journal of Chemical Crystallography. 38(6), 437--445. Springer US.
Poola, B., Hunt, S. W., Wang, X., Richmond, M. G. (2008). New platinum compounds containing the diphosphine ligand 2-(ferrocenylidene)-4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (fbpcd): Synthesis, redox behavior, and X-ray diffraction structures of PtCl 2 (fbpcd) and Pt (mnt)(fbpcd). Polyhedron. 27(18), 3693--3699. Elsevier.
Poola, B., Carrano, C. J., Richmond, M. G. (2008). Reaction of 6-Methyl-2, 2′-bipyridine with 1, 2-Os3 (CO) 10 (MeCN) 2: Syntheses, Reductive Elimination/Ligand Displacement Kinetics, and X-ray Diffraction Structures of the Isomeric Clusters HOs3 (CO) 9 ($\mu$2-N2C11H9) and H2Os3 (CO) 8 ($\mu$3-N2C11H8). Organometallics. 27(13), 3018--3028. American Chemical Society.
Nesterov, V., Watson, W., Kandala, S., Richmond, M. G. (2007). "CO Substitution in H4Ru4(CO)12 by the Diphosphine Ligands 1,2-Bis(diphenylphosphine)benzene (dppbz) and 1,8-Bis(diphenylphosphino)naphthalene (dppn): X-ray Diffraction Structures of the Diphosphine-chelated Clusters 1,1‑H4Ru4(CO)10(dppbz) and 1,1‑H4Ru4(CO)10(dppn),". Polyhedron.
Watson, W., Kandala, S., Richmond, M. G. (2007). "Ligand Chelation, P-C Bond Cleavage, and Phenyl-Group Transfer in the Reaction Between RCCo3(CO)9 and 1,8-Bis(diphenylphosphino)naphthalene (dppn): Syntheses and X-ray Diffraction Structures of PhCCo3(CO)4(μ-CO)3(dppn) and PhCCo3(CO)8[η1-PPh(OH)C10H6P(O)Ph2],". Journal of Organometallic Chemistry.
Watson, W., Kandala, S., Richmond, M. G. (2007). "Ligand Degradation and Phosphorus Scavenging in the Reaction Between 1,2-Bis(diphenylphosphino)benzene (dppbz) and Ru6(μ6-C)(CO)17: Synthesis and X-ray Structure of the Edge-bridged Square-pyramidal Cluster HRu6(μ5-C)(μ3-P)(CO)14(dppbz),". Journal of Organometallic Chemistry.
Watson, W., Strugatskiy, A., Wu, G., Richmond, M. G. (2007). "Photochemical Reactivity of the Triosmium Cluster 1,1-Os3(CO)10(bpcd) in the Presence of P(OEt)3 and X-ray Crystal Structure of HOs3(CO)7[P(OEt)3][μ-{PPh(C<sub>6</sub>H<sub>4</sub>)}C=C(PPh2)C(O)CH2C(O)]: Evidence for Ortho Metalation and Cluster Face Capping by a Diphosphine Ligand,". Journal of Chemical Crystallography.
Bott, S., Shen, H., Richmond, M. G. (2007). "Photochemically Promoted Regiospecific P-C Bond Cleavage in the Diruthenium Compound Ru2(CO)2(bmf): X-ray Diffraction Structure of Ru2(CO)6[μ-C=C(PPh2)C(O)OCH(OMe)](μ-PPh2),". Journal of Coordination Chemistry.
Nesterov, V., Poola, B., Wang, X., Richmond, M. G. (2007). "Pincer Ligand Coordination at a Triosmium Cluster: X-ray Structures of 1,2-Os3(CO)10[4,6-bis(diphenylphosphinomethyl)-m-xylene] and 1,2-Os3(CO)10[1-diphenylphosphino-1-{(2,4-dimethyl-5-diphenylphosphinomethyl)phenyl}-propan-2-ol],". Journal of Organometallic Chemistry.
Watson, W., Poola, B., Liu, J., Richmond, M. G. (2007). "Pincer Ligand Coordination at Co3 and Ru6 Clusters: Syntheses, Reactivity Studies, and X‑ray Diffraction Structures of [PhCCo3(CO)8]2(dppx) and [Ru6(μ6-C)(CO)16]2(dppx),". Journal of Chemical Crystallography.
Bott, S., Yang, K., Richmond, M. G. (2007). "PMe3-induced CO Insertion and CO Deinsertation in the Zwitterionic Hydrocarbyl Complex Co2(CO)4[μ-PhC=C(H)PPh2C=C(PPh2)C(O)OC(O)]. Syntheses and X-ray Structures of Co2(CO)3(PMe3)[μ-PhC(CO)=C(H)PPh2C=C(PPh2)C(O)OC(O)] and Co2(CO)3(PMe3)[μ-PhC=C(H)PPh2C=C(PPh2)C(O)OC(O)],". Polyhedron.
Bott, S., Shen, H., Kandala, S., Phan, N., Richmond, M. G. (2007). "Reaction of HRu3(CO)10(μ-COMe) with bma: NMR and X-ray Structural Evidence for the Formation of the Ph2PH-substituted Cluster HRu3(CO)8(PHPh2)[μ-PPh2C=CC(O)OC(O)],". Journal of Coordination Chemistry.
Watson, W., Poola, B., Richmond, M. G. (2007). "Regiospecific Alkyne Insertion into the Co-Co Bond of the Mixed-metal Cluster Co2Rh2(CO)12 by an Electron-poor Alkyne: X-ray Diffraction Structure of the Butterfly Cluster Co2Rh2(CO)10(μ-HCCCO2Me),". Polyhedron.
Watson, W., Huang, S., Richmond, M. G. (2007). "Synthesis and Characterization of the Osmium Compound cis(CO)-ClOs(CO)2(bpcd)[C(O)Et],". Journal of Chemical Crystallography.
Watson, W., Poola, B., Richmond, M. G. (2007). "Synthesis and Reactivity Studies of the Diphosphine Ligand 2-(Ferrocenylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Bridge-to-Chelate Ligand Isomerization Kinetics in Os3(CO)10(fbpcd) and X-ray Diffraction Structure of the Ortho-Metalated Cluster HOs3(CO)9[μ-PhP(C6H4)C=C(PPh2)C(O)C=CH(C5H4FeCp)C(O)] ,". Polyhedron.
Watson, W., Wiedenfeld, D., Pingali, A., Poola, B., Richmond, M. G. (2007). "Synthesis, Electrochemistry, MO Properties, and X‑ray Diffraction Structures of the New redox-active Diphosphine Ligand 2-(2-Thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (tbpcd) and fac-BrRe(CO)3(tbpcd),". Polyhedron.
Poola, B., Wang, X., Richmond, M. G. (2007). "α-Diimine Chelation at a Triosmium Cluster: Synthesis and X-ray Structure of 1,1-Os3(CO)9(μ-CO)(1,10-phen),". Journal of Chemical Crystallography.
Poola, B., Wang, X., Richmond, M. G. (2007). $\alpha$-Diimine Chelation at a Triosmium Cluster: Synthesis and X-ray Structure of 1, 1-Os 3 (CO) 9 ($\mu$-CO)(1, 10-phen). Journal of Chemical Crystallography. 37(9), 641--644. Springer US.
Nesterov, V. N., Watson, W. H., Kandala, S., Richmond, M. G. (2007). CO substitution in H 4 Ru 4 (CO) 12 by the diphosphine ligands 1, 2-bis (diphenylphosphino) benzene (dppbz) and 1, 8-bis (diphenylphosphino) naphthalene (dppn): X-ray diffraction structures of the diphosphine-chelated clusters 1, 1-H 4 Ru 4 (CO) 10 (dppbz) and 1, 1-H 4 Ru 4 (CO) 10 (dppn). Polyhedron. 26(14), 3602--3608. Elsevier.
Watson, W. H., Kandala, S., Richmond, M. G. (2007). Ligand chelation, P--C bond cleavage, and phenyl-group transfer in the reaction between RCCo 3 (CO) 9 and 1, 8-bis (diphenylphosphino) naphthalene (dppn): Syntheses and X-ray diffraction structures of PhCCo 3 (CO) 4 ($\mu$-CO) 3 (dppn) and PhCCo 3 (CO) 8 [$\eta$ 1-PPh (OH) C 10 H 6 P (O) Ph 2]. Journal of Organometallic Chemistry. 692(5), 968--975. Elsevier.
Watson, W. H., Strugatskiy, A., Wu, G., Richmond, M. G. (2007). Photochemical reactivity of the triosmium cluster 1, 1-Os 3 (CO) 10 (bpcd) in the presence of P (OEt) 3 and X-ray crystal structure of HOs 3 (CO) 7 [P (OEt) 3][$\mu$-$\{$PPh (C 6 H 4)$\}$ C= C (PPh 2) C (O) CH 2 C (O)]: Unexpected ortho metalation and cluster face capping by a diphosphine ligand. Journal of Chemical Crystallography. 37(4), 247--253. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Shen, H., Richmond, M. G. (2007). Photochemically promoted regiospecific P--C bond cleavage in the diruthenium compound Ru2 (CO) 2 (bmf): X-ray diffraction structure of Ru2 (CO) 6 [$\mu$-C= C (PPh2) C (O) OCH (OMe)]($\mu$-PPh2). Journal of Coordination Chemistry. 60(13), 1457--1467. Taylor \& Francis.
Nesterov, V., Poola, B., Wang, X., Richmond, M. G. (2007). Pincer ligand coordination at a triosmium cluster: X-ray structures of 1, 2-Os 3 (CO) 10 [4, 6-bis (diphenylphosphinomethyl)-m-xylene] and 1, 2-Os 3 (CO) 10 [1-diphenylphosphino-1-$\{$(2, 4-dimethyl-5-diphenylphosphinomethyl) phenyl$\}$-propan-2-ol]. Journal of Organometallic Chemistry. 692(9), 1806--1811. Elsevier.
Watson, W. H., Poola, B., Liu, J., Richmond, M. G. (2007). Pincer ligand coordination at Co 3 and Ru 6 clusters: Syntheses, reactivity studies, and X-ray diffraction structures of [PhCCo 3 (CO) 8] 2 (dppx) and [Ru 6 ($\mu$ 6-C)(CO) 16] 2 (dppx). Journal of Chemical Crystallography. 37(5), 349--358. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2007). PMe 3-induced CO insertion and CO deinsertion in the zwitterionic hydrocarbyl complex Co 2 (CO) 4 [$\mu$-PhC C (H) PPh 2 C C (PPh 2) C (O) OC (O)]: Syntheses and X-ray structures of Co 2 (CO) 3 (PMe 3)[$\mu$-PhC (CO) C (H) PPh 2 C C (PPh 2) C (O) OC (O)] and Co 2 (CO) 3 (PMe 3)[$\mu$-PhC C (H) PPh 2 C C (PPh 2) C (O) OC (O)]. Polyhedron. 26(14), 3737--3742. Elsevier.
BOTT, S., YANG, K., RICHMOND, M. (2007). PME3-INDUCED CO INSERTION AND CO DEINSERTION IN THE ZWITTERIONIC HYDROCARBYL COMPLEX CO2 (CO) 4 [$\mu$-PHC $\{$DOUBLE BOND, LONG$\}$ C (H) PPH2C $\{$DOUBLE BOND, LONG$\}$ C (PPH2) C (O) OC (O)]: SYNTHESES AND X-RAY STRUCTURES OF CO2 (CO) 3 (PME3)[$\mu$-PHC (CO)$\{$DOUBLE BOND, LONG$\}$ C (H) PPH2C $\{$DOUBLE BOND,.... Polyhedron. 26(14), 3737--3742. Elsevier Science Publishing Company, Inc..
Bott, S. G., Shen, H., Kandala, S., Phan, N. H., Richmond, M. G. (2007). Reaction of HRu3 (CO) 10 ($\mu$-COMe) with bma: NMR and X-ray structural evidence for the formation of the Ph2PH-substituted cluster HRu3 (CO) 8 (Ph2PH)[$\mu$-PPh2C= CC (O) OC (O)]. Journal of Coordination Chemistry. 60(11), 1223--1232. Taylor \& Francis.
Watson, W. H., Poola, B., Richmond, M. G. (2007). Regiospecific insertion into the Co--Co bond of the mixed-metal cluster Co 2 Rh 2 (CO) 12 by an electron-poor alkyne: X-ray diffraction structure of the butterfly cluster Co 2 Rh 2 (CO) 10 ($\mu$-HCCCO 2 Me). Polyhedron. 26(5), 1117--1122. Elsevier.
Watson, W. H., Poola, B., Richmond, M. G. (2007). Synthesis and reactivity studies of the diphosphine ligand 2-(ferrocenylidene)-4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (fbpcd): Bridge-to-chelate ligand isomerization kinetics in Os 3 (CO) 10 (fbpcd) and X-ray diffraction structure of the ortho-metalated cluster HOs 3 (CO) 9 [$\mu$-PhP (C 6 H 4) C C (PPh 2) C (O) C CH (C 5 H 4 FeCp) C (O)]. Polyhedron. 26(14), 3585--3594. Elsevier.
Watson, W., Kandala, S., Richmond, M. G. (2006). "Chlorine-Atom Abstraction and Cluster Fragmentation in the Reaction of H3Re3(CO)10(MeCN)2 with the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray Diffraction Structure of fac-ClRe(CO)3(bpcd),". Journal of Chemical Crystallography.
Watson, W., Ejsmont, K., Liu, J., Richmond, M. G. (2006). "CO Replacement in the Tetrahedrane Cluster MeC(O)CCo3(CO)9 by the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine Ligand Isomerization and X-ray Structure of the Bridged Cluster MeC(O)CCo3(CO)7(bpcd),". Journal of Chemical Crystallography.
Watson, W., Wu, G., Richmond, M. G. (2006). "Diphosphine Isomerization and C-H and P-C Bond Cleavage Reactivity in the Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X‑ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne-substituted Cluster HOs3(CO)8(μ3-C6H4)[μ2,η1-PPhC=C(PPh2)C(O)CH2C(O)],". Organometallics Journals.
Watson, W., Kandala, S., Richmond, M. G. (2006). "Diphosphine Ligand Substitution in H4Ru4(CO)12. X-ray Diffraction Structures and Reactivity Studies of the Cluster Compounds H4Ru4(CO)10(P-P) [where P-P = (Z)-Ph2PCH=CHPPh2, bpcd],". Journal of Chemical Crystallography.
Watson, W., Kandala, S., Richmond, M. G. (2006). "Diverse Ligand Substitution Behavior in the Reaction of H4Os4(CO)12 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) and Me3NO: Spectroscopic Characterization of the Diphosphine Chelating and Bridging Isomers H4Os4(CO)10(bpcd) and the X-ray Diffraction Structures of the Tetraosmium Clusters H4Os4(CO)11(NMe3) and H4Os4(CO)10(NMe3)(η1-bpcd),". Journal of Chemical Crystallography.
Richmond, M. G., Kandala, S. (2006). "Dynamic Behavior of the Diphosphine Ligand in H4Ru4(CO)10(dppe) Revisited: Kinetic Data Supporting a Nondissociative Isomerization of the Dppe Ligand,". Inorganic Chemistry.
Watson, W., Poola, B., Richmond, M. G. (2006). "Knoevenagel Condensation of the Diphosphine Ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione with 9-Anthracenecarboxaldehyde: Synthesis of the Second-Generation Ligand 2-(Anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione,". Journal of Chemical Crystallography.
Watson, W., Bodige, S., Ejsmont, K., Liu, J., Richmond, M. G. (2006). "Ligand Substitution in HC(O)CCo3(CO)9 with 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine Ligand Fluxionality, Decarbonylation of the Formyl Moiety and Competitive P-Ph Bond Cleavage Reactivity,". Journal of Organometallic Chemistry.
Watson, W., Poola, B., Richmond, M. G. (2006). "Ligand Substitution in the Tetrahedrane Clusters RCCo2Mo(η5-indenyl)(CO)8 with 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Influence of the Carbyne and Indenyl Ligands on the Stability of the Substitution Products and X-ray Diffraction Structures of HCCo2Mo(η5-indenyl)(CO)6(μ-bpcd) and CoMo(η5-indenyl)(μ-CPh)(CO)2(μ-bpcd)Cl,". Journal of Organometallic Chemistry.
Watson, W., Ejsmont, K., Liu, J., Richmond, M. G. (2006). "Ligand-induced Polyhedral Opening in the Mixed-metal Cluster MeCCo2NiCp(CO)6 by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray Structure of Co2NiCp(CO)4[μ2,η2,η1-C(Me)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2),". Journal of Chemical Crystallography.
Bott, S., Yang, K., Richmond, M. G. (2006). "Regiospecific and Sequential P-C Bond Activation/Cluster Transformations in the Reaction of PhCCo2MoCp(CO)8 with the Diphosphine Ligands 2,3-Bis(diphenylphosphino)maleic anhydride (bma) and 3,4-Bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf),". Journal of Organometallic Chemistry.
Watson, W., Poola, B., Richmond, M. G. (2006). "Syntheses and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(dmpe),". Journal of Chemical Crystallography.
Watson, W., Poola, B., Richmond, M. G. (2006). "Synthesis and Diphosphine Ligand Fluxionality in Os3(CO)10(bmi): Kinetic Evidence for Nondissociative Diphosphine Isomerization and X-ray Crystal Structure of 1,1‑Os3(CO)10(bmi),". Journal of Organometallic Chemistry.
Bott, S., Yang, K., Richmond, M. G. (2006). "Synthesis of the Chiral Tetrahedral Clusters RCCo2NiCp(CO)4(bmf) (R = H, Ph) and Thermally Promoted Diphosphine Ligand Activation: Regiospecific P-C Bond Scission and X-ray Diffraction Structure of Co2NiCp(CO)4[μ2,η2,η1-C(H)C=C(PPh2)C(O)OCH(OMe)](μ-PPh2),". Journal of Organometallic Chemistry.
Watson, W. H., Kandala, S., Richmond, M. G. (2006). Chlorine-atom abstraction and cluster fragmentation in the reaction of H 3 Re 3 (CO) 10 (MeCN) 2 with the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd): X-ray diffraction structure of fac-ClRe (CO) 3 (bpcd). Journal of Chemical Crystallography. 36(1), 71--75. Springer US.
Watson, W. H., Ejsmont, K., Liu, J., Richmond, M. G. (2006). CO replacement in the tetrahedrane cluster MeC (O) CCo 3 (CO) 9 by the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopenten-l, 3-dione (bpcd): Diphosphine ligand isomerization and X-ray structure of the bridged cluster MeC (O) CCo 3 (CO) 7 (bpcd). Journal of Chemical Crystallography. 36(8), 509--515. Springer US.
Watson, W. H., Wu, G., Richmond, M. G. (2006). Diphosphine Isomerization and C- H and P- C Bond Cleavage Reactivity in the Triosmium Cluster Os3 (CO) 10 (bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3 (CO) 10 (bpcd) and the Benzyne-Substituted Cluster HOs3 (CO) 8 ($\mu$3-C6H4)[$\mu$2, $\eta$1-PPhC C (PPh2) C (O) CH2C (O)]. Organometallics. 25(4), 930--945. ACS Publications.
Watson, W. H., Kandala, S., Richmond, M. G. (2006). Diverse ligand substitution behavior in the reaction of H 4 Os 4 (CO) 12 with 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) and Me 3 NO: Spectroscopic characterization of the diphosphine chelating and bridging isomers H 4 Os 4 (CO) 10 (bpcd) and the X-ray diffraction structures of the tetraosmium clusters H 4 Os 4 (CO) 11 (NMe 3) and 1, 2-H 4 Os 4 (CO) 10 (NMe 3)($ $$\backslash$eta\^$\{$1$\}$ $ $-bpcd). Journal of Chemical Crystallography. 36(10), 605--612. Kluwer Academic Publishers-Plenum Publishers.
Kandala, S., Richmond, M. G. (2006). Dynamic Behavior of the Diphosphine Ligand in H4Ru4 (CO) 10 (dppe) Revisited: Kinetic Data Supporting a Nondissociative Isomerization of the Dppe Ligand. Inorganic Chemistry. 45(15), 5976--5979. ACS Publications.
Watson, W. H., Poola, B., Richmond, M. G. (2006). Knoevenagel condensation of the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopentene-1, 3-dione with 9-anthracenecarboxaldehyde: Synthesis of the second-generation ligand 2-(anthracen-9-ylidene)-4, 5-bis (diphenylphosphino)-4-cyclopentene-1, 3-dione. Journal of Chemical Crystallography. 36(11), 715--722. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Ejsmont, K., Liu, J., Richmond, M. G. (2006). Ligand-induced polyhedral opening in the mixed-metal cluster MeCCo 2 NiCp (CO) 6 by 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd): X-ray structure of Co 2 NiCp (CO) 4 [$\mu$ 2, $\eta$ 2, $\eta$ 1-C (Me) C= C (PPh 2) C (O) CH 2 C (O)]($\mu$ 2-PPh 2). Journal of Chemical Crystallography. 36(12), 823--830. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2006). Regiospecific and sequential P--C bond activation/cluster transformations in the reaction of PhCCo 2 MoCp (CO) 8 with the diphosphine ligands 2, 3-bis (diphenylphosphino) maleic anhydride (bma) and 3, 4-bis (diphenylphosphino)-5-methoxy-2 (5H)-furanone (bmf). Journal of Organometallic Chemistry. 691(18), 3771--3781. Elsevier.
Watson, W. H., Poola, B., Richmond, M. G. (2006). Syntheses and X-ray structures of the bridging and chelating isomers of Os 3 (CO) 10 (dmpe). Journal of Chemical Crystallography. 36(2), 123--128. Springer US.
Wu, G. (2006). Synthesis and Characterization of 2, 3-Dichloropyrrolo [1, 2-a] benzimidazol-1-one and Its Methylthiol Derivatives. University of North Texas.
Bott, S. G., Yang, K., Richmond, M. G. (2006). Synthesis of the chiral tetrahedral clusters RCCo 2 NiCp (CO) 4 (bmf)(R= H, Ph) and thermally promoted diphosphine ligand activation: Regiospecific P--C bond scission and X-ray diffraction structure of Co 2 NiCp (CO) 4 [$\mu$ 2, $\eta$ 2, $\eta$ 1-C (H) C C (PPh 2) C (O) OCH (OMe)]($\mu$-PPh 2). Journal of Organometallic Chemistry. 691(1), 20--26. Elsevier.
Watson, W. H., Wu, G., Vadapally, P., Richmond, M. G. (2006). Synthesis, redox properties, and molecular structure of 4, 5-diethylthio-4-cyclopenten-1, 3-dione: Cyclic voltammetric evidence for a kinetically stable radical anion. Journal of Chemical Crystallography. 36(1), 55--60. Springer US.
Watson, W., Wu, G., Vadapally, P., Richmond, M. G. (2006). Synthesis, Redox Properties, and Molecular Structure of 4,5-Diethylthio-4-cyclopenten-1,3-dione: Cyclic Voltammetric Evidence for a Kinetically Stable Radical Anion,". Journal of Chemical Crystallography.
Watson, W., Liu, J., Richmond, M. G. (2005). "Alkyne Insertion and Coupling Reactions of Methyl Propiolate with the Heterometallic Dimers CoRu(CO)7(μ-PPh2) and CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2): X-ray Diffraction Structures of CoRu(CO)4(μ-CO)[μ-PPh2C(O)CH(CCO2Me)C(O)CHC(CO2Me)] and CoRu(CO)3(μ-CO)[(Z)-Ph2PCH=CHPPh2][μ-PPh2C(O)C(CO2Me)CH],". Journal of Chemical Crystallography.
Watson, W., Poola, B., Richmond, M. G. (2005). "Dimethyl Acetylenedicarboxylate (dmad) Reactivity with the Mixed-Metal Cluster Co2Rh2(CO)12: Facile Cluster Fragmentation and Highly Specific Metal Redistribution to Give the Butterfly Cluster Co3Rh(CO)10(μ-dmad) and the Planar Cluster CoRh3(CO)9(μ-dmad)3,". Organometallics Journals.
Bott, S., Yang, K., Richmond, M. G. (2005). "Ligand Substitution in the Mixed-Metal Cluster PhCCo2Ni(CO)6Cp by 2,3-Bis(diphenylphosphino)maleic Anhydride (bma): An Intimate Picture Involving the Stepwise Conversion of the Trinuclear Cluster PhCCo2Ni(CO)4(η2-bma)Cp to the Mononuclear Metallocyclic Compound CpNi[PPh2CPhC=C(PPh2)(O)OC(O)],. Journal of Organometallic Chemistry.
Richmond, M. G. (2005). "Organometallic Metal Cluster Chemistry for the Year 2003,". Journal of Coordination Chemistry.
Nalla, P., Huang, S., Zhang, Y., Chyan, O., Richmond, M. G. (2005). "Photochemically Induced Metallization of Surface Silicon Using Dinuclear Metal Carbonyl Compounds. Anchoring of Ruthenium to a Si(111) Surface Through Covalent Ru-Si Bond Formation,". Chemistry of Materials.
Bott, S., Lee, S., Yang, K., Richmond, M. G. (2005). "Polyene Ring Attack in diag-CpRe(CO)2Br2 by Hydride and Cyclopentadiene Displacement to Furnish trans(Br)-[Re(CO)4Br2]- Under CO. X-ray Diffraction Structure of trans(Br)-[Re(CO)4Br2][PPh4],". Journal of Chemical Crystallography.
Wu, G., Glass, D., May, D., Watson, W., Wiedenfeld, D., Richmond, M. G. (2005). "Reaction of 2,3-Bis(methylthio)pyrrolo[1,2-a]benzimidazol-1-one with BrRe(CO)3(THF)2. X-ray Diffraction Structure, Redox Chemistry, and Luminescence Behavior of fac‑BrRe(CO)3{N,S-2,3-bis(methylthio)pyrrolo[1,2-<i>a</i>]benzimidazol-1-one},". Journal of Organometallic Chemistry.
Bott, S., Shen, H., Richmond, M. G. (2005). "Reversible Aryl C-H Bond Activation in the Reaction Between HRu3(CO)9,10(μ-PPh2) and the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X‑ray Diffraction Structures of H2Ru3(CO)7(bpcd)[μ,σ-PPh(C6H4)] and Ru3(CO)6(μ-CO)(μ-PPh2)[μ,η2,η1-PPhC=C(PPh2)C(O)CH2C(O)],". Journal of Organometallic Chemistry.
Watson, W., Wu, G., Richmond, M. G. (2005). "Reversible Isomerization of a Diphosphine Ligand About a Triosmium Cluster: Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3(CO)10[(Z)-Ph2PCH=CHPPh2],". Organometallics Journals.
Bott, S., Yang, K., Richmond, M. G. (2005). "Synthesis, X-ray Diffraction Structure, and Redox Chemistry of Re2(CO)8(bmf),". Journal of Chemical Crystallography.
Watson, W., Kandala, S., Richmond, M. G. (2005). "Thermolysis of the Tetrahedrane Cluster PhCCo3(CO)3(μ-CO)Cp2 with the Unsaturated Diphosphine Ligands (Z)-Ph2PCH=CHPPh2 and 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Redox Properties and Molecular Structure of PhCCo3(CO)(μ-CO)[(Z)-Ph2PCH=CHPPh2]Cp2,". Journal of Chemical Crystallography.
Watson, W. H., Liu, J., Richmond, M. G. (2005). Alkyne insertion and coupling reactions of methyl propiolate with the heterometallic dimers CoRu (CO) 7 ($\mu$-PPh 2) and CoRu (CO) 5 [(Z)-Ph 2 PCH= CHPPh 2]($\mu$-PPh 2): X-ray diffraction structures of CoRu (CO) 4 ($\mu$-CO)[$\mu$-PPh 2 C (O) CH (CCO 2 Me) C (O) CHC (CO 2 Me)] and CoRu (CO) 3 ($\mu$-CO)[(Z)-Ph 2 PCH= CHPPh 2][$\mu$-PPh 2 C (O) C (CO 2 Me) CH]. Journal of Chemical Crystallography. 35(3), 249--258. Kluwer Academic Publishers-Plenum Publishers.
Richmond, M. G. (2005). Annual survey of organometallic metal cluster chemistry for the year 2003. Coordination Chemistry Reviews. 249(24), 2763--2786. Elsevier.
Watson, W. H., Poola, B., Richmond, M. G. (2005). Dimethyl Acetylenedicarboxylate (dmad) Reactivity with the Mixed-Metal Cluster Co2Rh2 (CO) 12: Facile Cluster Fragmentation and Highly Specific Metal Redistribution to Give the Butterfly Cluster Co3Rh (CO) 10 ($\mu$-dmad) and the Planar Cluster CoRh3 (CO) 9 ($\mu$-dmad) 3. Organometallics. 24(19), 4687--4690. ACS Publications.
Bott, S. G., Yang, K., Richmond, M. G. (2005). Ligand substitution in the mixed-metal cluster PhCCo 2 Ni (CO) 6 Cp by 2, 3-bis (diphenylphosphino) maleic anhydride (bma): An intimate picture involving the stepwise conversion of the trinuclear cluster PhCCo 2 Ni (CO) 4 ($\eta$ 2-bma) Cp to the mononuclear compound CpNi [PPh 2 CPhC C (PPh 2) C (O) OC (O)]. Journal of Organometallic Chemistry. 690(12), 3067--3079. Elsevier.
Nalla, P., Huang, S., Zhang, Y., Chyan, O., Richmond, M. G., El Bouanani, M. (2005). Photochemically Induced Metallization of Surface Silicon Using Dinuclear Metal Carbonyl Compounds. Anchoring of Ruthenium to a Si (111) Surface through Covalent Ru- Si Bond Formation. Chemistry of Materials. 17(24), 5951--5956. ACS Publications.
Bott, S. G., Lee, S., Yang, K., Richmond, M. G. (2005). Polyene ring attack in diag-CpRe (CO) 2 Br 2 by hydride and cyclopentadiene displacement to furnish trans (Br)-[Re (CO) 4 Br 2]- under CO: X-ray diffraction structure of trans (Br)-[Re (CO) 4 Br 2][PPh 4]. Journal of Chemical Crystallography. 35(3), 203--209. Kluwer Academic Publishers-Plenum Publishers.
Wu, G., Glass, D. R., May, D., Watson, W. H., Wiedenfeld, D., Richmond, M. G. (2005). Reaction of 2, 3-bis (methylthio) pyrrolo [1, 2-a] benzimidazol-1-one with BrRe (CO) 3 (THF) 2: X-ray diffraction structure, redox chemistry, and luminescence behavior of fac-BrRe (CO) 3 $\{$N, S-2, 3-bis (methylthio) pyrrolo [1, 2-a] benzimidazol-1-one$\}$. Journal of Organometallic Chemistry. 690(21), 4993--4999. Elsevier.
Bott, S. G., Shen, H., Richmond, M. G. (2005). Reversible aryl C--H bond activation in the reaction between HRu 3 (CO) 9, 10 ($\mu$-PPh 2) and the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd): X-ray diffraction structures of H 2 Ru 3 (CO) 7 (bpcd)[$\mu$, $\sigma$-PPh (C 6 H 4)] and Ru 3 (CO) 6 ($\mu$-CO)($\mu$-PPh 2)[$\mu$, $\eta$ 2, $\eta$ 1-PPhC C (PPh 2) C (O) CH 2 C (O)]. Journal of Organometallic Chemistry. 690(16), 3838--3845. Elsevier.
Watson, W. H., Wu, G., Richmond, M. G. (2005). Reversible Isomerization of a Diphosphine Ligand about a Triosmium Cluster: Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3 (CO) 10 [(Z)-Ph2PCH CHPPh2]. Organometallics. 24(22), 5431--5439. ACS Publications.
Bott, S. G., Yang, K., Richmond, M. G. (2005). Synthesis, X-ray diffraction structure, and redox chemistry of Re 2 (CO) 8 (bmf). Journal of Chemical Crystallography. 35(9), 709--716. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Kandala, S., Richmond, M. G. (2005). Thermolysis of the tetrahedrane cluster PhCCo 3 (CO) 3 ($\mu$-CO) Cp 2 with the unsaturated diphosphine ligands (Z)-Ph 2 PCH= CHPPh 2 and 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd): Redox properties and molecular structure of PhCCo 3 (CO)($\mu$-CO)[(Z)-Ph 2 PCH= CHPPh 2] Cp 2. Journal of Chemical Crystallography. 35(2), 157--165. Kluwer Academic Publishers-Plenum Publishers.
Bott, S., Yang, K., Huang, S., Richmond, M. G. (2004). "CO Substitution in the Mixed-metal Clusters PhCCo2Ni(CO)6Cp and PhCCo2Mo(CO)8Cp by (Z)-Ph2PCH=CHPPh2. X-ray Diffraction Structures and Proof of Ligand Bridging in PhCCo2Ni(CO)4[(Z)-Ph2PCH=CHPPh2]Cp and PhCCo2Mo(CO)6[(Z)-Ph2PCH=CHPPh2]Cp,". Journal of Chemical Crystallography.
Watson, W., Chen, T., Richmond, M. G. (2004). "Diphosphine Ring Expansion and π-Bond Reduction in the Reaction Between 1,2-Bis(diphenylphosphino)cyclobutenedione (bpcbd) and Ru3(CO)10(MeCN)2: X-ray Diffraction Structures of Ru3(CO)10[2,3-bis(diphenylphosphino)succinic anhydride]·CH2Cl2 and Ru2(CO)6(bma),". Journal of Chemical Crystallography.
Watson, W., Huang, S., Richmond, M. G. (2004). "Ligand Substitution in the Halo-bridged Diruthenium Compound [Ru(CO)3Cl2]2 by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Synthesis, Spectral Properties, and X-ray Diffraction Structures of RuCl2(CO)2(bpcd) and cis-RuCl[C(O)Et](CO)2(bpcd),". Journal of Chemical Crystallography.
Watson, W., Wu, G., Richmond, M. G. (2004). "New Polydentate Sulfide Ligands: Synthesis, Redox Properties, and Molecular Structure of 4,5-Bis(p-tolylthio)-4-cyclopenten-1,3-dione,". Journal of Chemical Crystallography.
Watson, W., Wu, G., Huang, S., Richmond, M. G. (2004). "New Sulfur Derivatives of 2,3-Dichloropyrrolo[1,2-a]benzimidazol-1-one. Demonstration of Regioselective Thiolate Addition and X-ray Diffraction Structures of 2-chloro-3-methylthiopyrrolo[1,2-a]benzimidazol-1-one and 2,3-Di(benzylthio)pyrrolo[1,2-a]benzimidazol-1-one,". Journal of Chemical Crystallography.
Richmond, M. G. (2004). "Organometallic Metal Cluster Chemistry for the Year 2002,". Journal of Coordination Chemistry.
Bott, S., Yang, K., Richmond, M. G. (2004). "Reaction of 1,2-Bis(diphenylphosphino)cyclobutenedione (bpcbd) with fac‑BrRe(CO)3(THF)2: X-ray Diffraction Structure of the Dimeric Complex [BrRe(CO)3]2(bpcbd)·CH2Cl2,". Journal of Chemical Crystallography.
Watson, W., Chen, T., Richmond, M. G. (2004). "Reaction of Dichloromaleic Anhydride and 1,8-Diaminonaphthalene: Synthesis and X‑ray Diffraction Structure of 8,9-Dichloropyrrolo[1,2-a]perimidin-10-one,". Journal of Chemical Crystallography.
Watson, W., Wu, G., Richmond, M. G. (2004). "Reaction of o-Phenylenediamine with 2,3-Dichloromaleic Anhydride: Synthesis of N-Substituted Maleimide Derivatives and 2,3-Dichloropyrrolo[1,2-a]benzimidazol-1-one. X-ray Structures of 2,3-Dichloro-N-o-C6H4(NH2)maleimide and N,N'-o-C6H4-Bis(2,3-dichloromaleimide),". Journal of Chemical Crystallography.
Xia, C., Bott, S., Wu, G., Richmond, M. G. (2004). "Reaction of the Dicobalt Alkyne Compound Co2(CO)6(μ-dmad) with the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Spectroscopic Properties, X-ray Diffraction Data, and Thermal Reactivity of the Chelating Isomer of Co2(CO)4(bpcd)(μ-dmad),". Journal of Chemical Crystallography.
Watson, W., Chen, T., Richmond, M. G. (2004). "Synthesis, Redox Properties, and X-ray Diffraction Structure of 2,3-Bis(ethylthio)-N-(p-MeOC6H4)maleimide,". Journal of Chemical Crystallography.
Bott, S., Shen, H., Richmond, M. G. (2004). "Thermally Induced Dual P-C Bond Cleavage Routes from the Imido-capped Cluster Ru3(CO)7(μ3-CO)(μ3-NPh)(bpcd). Synthesis, Spectroscopic Properties, and X-ray Diffraction Structures of Ru3(CO)7(μ3-CO)(μ3-NPh)(bpcd), Ru3(CO)5(μ2-CO)2(μ3-NPh)(μ2-PPh2)[μ-η1,η1-C=C(PPh2)C(O)CH2C(O)], Ru3(CO)6(μ2-CO)(μ3-NPh)(μ-PhCO)[μ2-η2,η1-PPhC=C(PPh2)C(O)CH2C(O)], and Ru3(CO)9(μ3-NPh)(μ3-PPh),". Journal of Organometallic Chemistry.
Watson, W., Wu, G., Richmond, M. G. (2004). "Unexpected Chlorine Substitution by Hydrogen in the Reaction of 2-Chloro-3-p-toluidino-N-p-tolylmaleimide with DBU: Synthesis and Molecular Structure of 2-p-toluidino-N-p-tolylmaleimide,". Journal of Chemical Crystallography.
Bott, S., Yang, K., Richmond, M. G. (2004). "Unusual Chemical Reactivity in the Reactions of Re2(CO)8(μ-H)(μ-η1,η2-CH=CHBu) with 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) and Re2(CO)8(bma) with Ni(cod)2: X-ray Diffractions Structures of Re2(CO)8(bma), Zwitterionic Re(CO)4[Re(CO)4(bma)], and the Phosphido-bridged Complex Re2(CO)8[μ-η1,η1-C=C(PPh2)C(O)OC(O)](μ-PPh2),". Journal of Organometallic Chemistry.
Richmond, M. G. (2004). Annual survey of organometallic metal cluster chemistry for the year 2002. Coordination Chemistry Reviews. 248(9-10), 881--901. Elsevier.
Bott, S. G., Yang, K., Huang, S., Richmond, M. G. (2004). CO substitution in the mixed-metal clusters PhCCo 2 Ni (CO) 6 Cp and PhCCo 2 Mo (CO) 8 Cp by (Z)-Ph 2 PCH= CHPPh 2. X-ray diffraction structures and proof of ligand bridging in PhCCo 2 Ni (CO) 4 [(Z)-Ph 2 PCH= CHPPh 2] Cp and PhCCo 2 Mo (CO) 6 [(Z)-Ph 2 PCH= CHPPh 2] Cp. Journal of Chemical Crystallography. 34(12), 883--891. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Chen, T., Richmond, M. G. (2004). Diphosphine ring expansion and $\pi$-bond reduction in the reaction between 1, 2-bis (diphenylphosphino) cyclobutenedione (bpcbd) and Ru 3 (CO) 10 (MeCN) 2: X-ray diffraction structures of Ru 3 (CO) 10 [2, 3-bis (diphenylphosphino) succinic anhydride] and Ru 2 (CO) 6 (bma). Journal of Chemical Crystallography. 34(11), 797--805. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Huang, S., Richmond, M. G. (2004). Ligand substitution in the halo-bridged diruthenium compound [Ru (CO) 3 Cl 2] 2 by 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Synthesis, spectral properties, and X-ray diffraction structures of cis (CO), trans (Cl)-RuCl 2 (CO) 2 (bpcd) and cis (CO)-RuCl [C (O) Et](CO) 2 (bpcd). Journal of Chemical Crystallography. 34(9), 627--635. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Wu, G., Richmond, M. G. (2004). New polydentate sulfide ligands: Synthesis, redox properties, and molecular structure of 4, 5-bis (p-tolylthio)-4-cyclopenten-1, 3-dione. Journal of Chemical Crystallography. 34(10), 709--716. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2004). Reaction of 1, 2-bis (diphenylphosphino) cyclobutenedione (bpcbd) with fac-BrRe (CO) 3 (THF) 2: X-ray diffraction structure of the dimeric complex [BrRe (CO) 3] 2 (bpcbd)⋅ CH 2 Cl 2. Journal of Chemical Crystallography. 34(2), 127--133. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Wu, G., Richmond, M. G. (2004). Reaction of o-phenylenediamine with 2, 3-dichloromaleic anhydride: synthesis of N-substituted maleimide derivatives and 2, 3-dichloropyrrolo [1, 2-a] benzimidazol-1-one. X-ray structures of 2, 3-dichloro-N-o-C 6 H 4 (NH 2) maleimide and N, N′-o-C 6 H 4-bis (2, 3-dichloromaleimide). Journal of Chemical Crystallography. 34(11), 757--764. Kluwer Academic Publishers-Plenum Publishers.
Xia, C., Bott, S. G., Richmond, M. G. (2004). Reaction of the dicobalt alkyne compound Co 2 (CO) 6 ($\mu$-dmad) with the diphosphine ligand 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Spectroscopic properties, X-ray diffraction data, and thermal reactivity of the chelating isomer of Co 2 (CO) 4 (bpcd)($\mu$-dmad). Journal of Chemical Crystallography. 34(8), 513--521. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Chen, T., Richmond, M. G. (2004). Synthesis, redox properties, and X-ray diffraction structure of 2, 3-bis (ethylthio)-N-(p-MeOC 6 H 4) maleimide. Journal of Chemical Crystallography. 34(11), 765--771. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Shen, H., Richmond, M. G. (2004). Thermally induced dual P--C bond cleavage routes from the imido-capped cluster Ru 3 (CO) 7 ($\mu$ 3-CO)($\mu$ 3-NPh)(bpcd): synthesis, spectroscopic properties, and X-ray diffraction structures of Ru 3 (CO) 7 ($\mu$ 3-CO)($\mu$ 3-NPh)(bpcd), Ru 3 (CO) 5 ($\mu$ 2-CO) 2 ($\mu$ 3-NPh)($\mu$ 2-PPh 2)[$\mu$, $\eta$ 1, $\eta$ 1-C C (PPh 2) C (O) CH 2 C (O)], Ru 3 (CO) 6 ($\mu$ 2-CO)($\mu$ 3-NPh)($\mu$-PhCO)[$\mu$ 2, $\eta$ 2, $\eta$ 1-PPhC C (PPh 2) C (O) CH 2 C (O)], and Ru 3 (CO) 9 ($\mu$ 3-NPh)($\mu$ 3-PPh). Journal of Organometallic Chemistry. 689(21), 3426--3437. Elsevier.
Watson, W. H., Wu, G., Richmond, M. G. (2004). Unexpected chlorine substitution by hydrogen in the reaction of 2-chloro-3-p-toluidino-N-p-tolylmaleimide with DBU: Synthesis and molecular structure of 2-p-toluidino-N-p-tolylmaleimide. Journal of Chemical Crystallography. 34(9), 621--625. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2004). Unusual chemical reactivity in the reactions of Re 2 (CO) 8 ($\mu$-H)($\mu$-$\eta$ 1, $\eta$ 2-CH CHBu) with 2, 3-bis (diphenylphosphino) maleic anhydride (bma) and Re 2 (CO) 8 (bma) with Ni (cod) 2: X-ray diffraction structures of Re 2 (CO) 8 (bma), zwitterionic Re (CO) 4 [Re (CO) 4 (bma)], and the phosphido-bridged complex Re 2 (CO) 8 [$\mu$-$\eta$ 1, $\eta$ 1-(O)]($\mu$-PPh 2). Journal of Organometallic Chemistry. 689(4), 791--800. Elsevier.
Bott, S., Shen, H., Senter, R., Richmond, M. G. (2003). "Acetylide Participation in Ligand Substitution and P-C Bond Cleavage in the Reaction Between HRu3(CO)9(μ3,η2,η2,η1-C º CPh) and 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses and X-ray Structures of HRu3(CO)7[μ3,η2,η2,η1,η1,η1-Ph2PC=CC(O)CH2C(O)PPh2C=CPh] and Ru3(CO)6(μ,η2,η1-PhC=CHPh)[μ2,η2,η1-PPhC=CC(O)CH2C(O)PPh2]. Organometallics Journals.
Watson, W., Ejsmont, K., Liu, J., Richmond, M. G. (2003). "CO Substitution in Ru3(CO)12 by 2,3-Bis(diphenylphosphino)-N-phenylmaleimide (bppm). X-ray Diffraction Structure of Ru2(CO)6(bppm),". Journal of Chemical Crystallography.
Watson, W., Wang, J., Richmond, M. G. (2003). "Construction of a Hexanuclear Cluster Composed of Spatially Separated Co3 and Ru3 Units. X-ray Diffraction Structure of Co3(CO)9[μ3‑CCO2CH2CC{HRu<sub>3</sub>(CO)<sub>9</sub>}],". Journal of Chemical Crystallography.
Watson, W., Bodige, S., Liu, J., Richmond, M. G. (2003). "ETC and Thermal Ligand Substitution in PhCCo3(CO)9 with 2,3-Bis(diphenylphosphino)-N-phenylmaleimide (bppm). X-ray Diffraction Structure of Co3(CO)6[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)NPhC(O)](μ2-PPh2),". Structural Chemistry.
Richmond, M. G. (2003). "Organometallic Metal Cluster Chemistry for the Year 2001,". Journal of Coordination Chemistry.
Watson, W., Don, M., Richmond, M. G. (2003). "Ortho-Metalation and Carboxylate Coordination in the Reaction Between the Dipotassium Salt of Phthalic Acid and Cp*Ir(PMe3)Cl2: X-ray Diffraction Structure of Cp*Ir(PMe3)[C6H3(CO2)(CO2H)],". Journal of Chemical Crystallography.
Bott, S., Yang, K., Talafuse, K., Richmond, M. G. (2003). "Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo2NiCp(CO)6 by 2,3-Bis(diphenylphosphino)maleic anhydride (bma). P-C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co2NiCp(CO)4(μ-CO)[μ2,η2,η1-C(H)PPh2C=C(PPh2)C(O)OC(O)] and Co2NiCp(CO)4[μ2,η2,σ-C(H)PPh2C=CC(O)OC(O)](μ2-PPh2),". Organometallics Journals.
Bott, S., Múnoz, T., Richmond, M. G. (2003). "Reaction of 2,3-Bis(diphenylphosphino)maleic acid-thioanhydride (bmata) with PhCCo3(CO)9. X-ray Diffraction Structure of Co3(CO)6[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)SC(O)](μ2-PPh2),". Journal of Chemical Crystallography.
Watson, W., Zhao, Y., Richmond, M. G. (2003). "Regiospecific CO Substitution in (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 by 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). X‑ray Structure of (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)7(bpcd)·MeOH,". Journal of Chemical Crystallography.
Xia, C., Bott, S., Richmond, M. G. (2003). "Regiospecific CO Substitution in (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 by 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). X‑ray Structure of (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)7(bpcd)·MeOH,". Journal of Chemical Crystallography.
Watson, W., Wu, G., Richmond, M. G. (2003). "Sequential Reaction of p-Toluidine with 2,3-Dichloromaleic Anhydride: Synthesis and Molecular Structure of 2-Chloro-3-p-toluidino-N-p-tolylmaleimide,". Journal of Chemical Crystallography.
Watson, W., Liu, J., Richmond, M. G. (2003). "Site-Selective Ligand Substitution in CoRu(CO)7(μ-PPh2) using (Z)-Ph2PCH=CHPPh2 and Reactivity of DMAD with CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2). X-ray Structures of CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2) and CoRu(CO)3(μ-CO)[(Z)-Ph2PCH=CHPPh2][μ,η3‑Ph2PC(CO2Me)C(CO2Me)],". Journal of Chemical Crystallography.
Bott, S., Yang, K., Richmond, M. G. (2003). "X-ray Diffraction Structure of (5S)-3,4-Dichloro-5-menthoxy-2(5H)-furanone,". Journal of Chemical Crystallography.
Watson, W., Bodige, S., Wang, J., Richmond, M. G. (2003). "X-ray Structure and Redox Chemistry of the Heptacobalt Cluster Co3(CO)9[μ3‑CCO2CH2CCH{Co<sub>4</sub>(CO)<sub>10</sub>}],". Journal of Chemical Crystallography.
Bott, S. G., Shen, H., Senter, R. A., Richmond, M. G. (2003). Acetylide Participation in Ligand Substitution and P- C Bond Cleavage in the Reaction between HRu3 (CO) 9 ($\mu$3, $\eta$2, $\eta$2, $\eta$1-C⋮ CPh) and 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Syntheses and X-ray Structures of HRu3 (CO) 7 [$\mu$3, $\eta$2, $\eta$2, $\eta$1, $\eta$1, $\eta$1-Ph2PC CC (O) CH2C (O) PPh2C CPh] and Ru3 (CO) 7 ($\mu$, $\eta$2, $\eta$1-PhC CHPh)[$\mu$2, $\eta$2, $\eta$1-PPhC CC (O) CH2C (O) PPh2]. Organometallics. 22(9), 1953--1959. ACS Publications.
Richmond, M. G. (2003). Annual survey of organometallic metal cluster chemistry for the year 2001. Coordination Chemistry Reviews. 241(1-2), 273--294. Elsevier.
Watson, W. H., Mendez-Rojas, M. A., Zhao, Y., Richmond, M. G. (2003). Bridging and chelating diphosphine ligands in Ru3 ($\mu$-H)($\mu$-N= CPh2)(CO) 8 (P—P). X-ray diffraction structures of Ru3 ($\mu$-H)($\mu$-N= CPh2)(CO) 8 (dmpe) and Ru3 ($\mu$-H)($\mu$-N= CPh2)(CO) 8 (bpcd). Journal of Chemical Crystallography. 33(10), 765--774. Kluwer Academic Publishers-Plenum Publishers.
Ejsmont, K., Watson, W. H., Liu, J., Richmond, M. G. (2003). CO substitution in Ru 3 (CO) 12 by 2, 3-bis (diphenylphosphino)-N-phenyl-maleimide (bppm). X-ray diffraction structure of Ru 2 (CO) 6 (bppm). Journal of Chemical Crystallography. 33(7), 541--547. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Wang, J., Richmond, M. G. (2003). Construction of a hexanuclear cluster composed of spatially separated Co 3 and Ru 3 units: X-ray diffraction structure of Co 3 (CO) 9 [$\mu$ 3-CCO 2 CH 2 CC $\{$HRu 3 (CO) 9$\}$]. Journal of Chemical Crystallography. 33(12), 957--962. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Bodige, S. G., Liu, J., Richmond, M. G. (2003). ETC and Thermal Ligand Substitution in PhCCo 3 (CO) 9 with 2, 3-Bis (diphenylphosphino)-N-phenylmaleimide (bppm). X-Ray Diffraction Structure of Co 3 (CO) 6 [$\mu$ 2, $\eta$ 2, $\eta$ 1-C (Ph) $ $ $ $(O)]($\mu$ 2-PPh 2). Structural Chemistry. 14(4), 369--375. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Don, M., Richmond, M. G. (2003). Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp* Ir (PMe 3) Cl 2: X-ray diffraction structure of Cp* Ir (PMe 3)[C 6 H 3 (CO 2)(CO 2 H)]. Journal of Chemical Crystallography. 33(12), 963--968. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Talafuse, K. A., Richmond, M. G. (2003). Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo2NiCp (CO) 6 by 2, 3-Bis (diphenylphosphino) maleic Anhydride (bma): P- C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co2NiCp (CO) 4 ($\mu$-CO)[$\mu$2, $\eta$2, $\eta$1-C (H) PPh2C C (PPh2) C (O) OC (O)] and Co2NiCp (CO) 4 [$\mu$2, $\eta$2, $\sigma$-C (H) PPh2C CC (O) OC (O)]($\mu$2-PPh2). Organometallics. 22(7), 1383--1390. ACS Publications.
Bott, S. G., Mu\~noz, Trinidad,, Richmond, M. G. (2003). Reaction of 2, 3-bis (diphenylphosphino) maleic acid-thioanhydride (bmata) with PhCCo 3 (CO) 9. X-ray diffraction structure of $ $$\{$$\backslash$text $\{$Co$\}$$\}$ \_ $\{$$\backslash$text $\{$3$\}$$\}$($\{$$\backslash$text $\{$CO)$\}$$\}$ \_ $\{$$\backslash$text $\{$6$\}$$\}$[$\backslash$mu \_2,$\backslash$eta\^ 2,$\backslash$eta\^ 1 $\{$$\backslash$text $\{$-C (Ph)$\}$$\}$$\{$$\backslash$text $\{$(O)]($\}$$\}$$\backslash$mu \_2 $\{$$\backslash$text $\{$-PPh$\}$$\}$ \_ $\{$$\backslash$text $\{$2$\}$$\}$) $ $. Journal of Chemical Crystallography. 33(7), 549--556. Kluwer Academic Publishers-Plenum Publishers.
Xia, C., Bott, S. G., Richmond, M. G. (2003). Regiospecific CO substitution in ($\mu$-H) Ru 3 ($\mu$ 3- $\eta$ 3-CHCHCMe)(CO) 9 by 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). X-ray structure of ($\mu$-H) Ru 3 ($\mu$ 3- $\eta$ 3-CHCHCMe)(CO) 7 (bpcd)⋅ MeOH. Journal of Chemical Crystallography. 33(9), 681--687. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Wu, G., Richmond, M. G. (2003). Sequential reaction of p-toluidine with 2, 3-dichloromaleic anhydride: Synthesis and molecular structure of 2-chloro-3-p-toluidino-N-p-tolylmaleimide. Journal of Chemical Crystallography. 33(12), 983--988. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Ejsmont, K., Liu, J., Richmond, M. G. (2003). Site-selective ligand substitution in CoRu (CO) 7 ($\mu$-PPh 2) using (Z)-Ph 2 PCH= CHPPh 2 and reactivity of DMAD with CoRu (CO) 5 [(Z)-Ph 2 PCH= CHPPh 2]($\mu$-PPh 2). X-ray structures of CoRu (CO) 5 [(Z)-Ph 2 PCH= CHPPh 2]($\mu$-PPh 2) and CoRu (CO) 3 ($\mu$-CO)[(Z)-Ph 2 PCH= CHPPh 2][$\mu$, $\eta$ 3-Ph 2 PC (CO 2 Me) C (CO 2 Me)]. Journal of Chemical Crystallography. 33(10), 775--785. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2003). X-ray diffraction structure of (5S)-3, 4-dichloro-5-menthoxy-2 (5H)-furanone. Journal of Chemical Crystallography. 33(7), 585--588. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Bodige, S., Wang, J., Richmond, M. G. (2003). X-ray structure and redox chemistry of the heptacobalt cluster Co 3 (CO) 9 [$\mu$ 3-CCO 2 CH 2 CCH $\{$Co 4 (CO) 10$\}$]. Journal of Chemical Crystallography. 33(9), 673--679. Kluwer Academic Publishers-Plenum Publishers.
Castellani, M., Hwang, S., Longacre, S., Rheingold, A., Richmond, M. G. (2002). "Ion-Pairing Thermodynamics for (η5-pentadienyl)Fe(CO)2- (pentadienyl = MeCp, C5Me5, C5Ph5, C9H7) and X-ray Crystal Structure of [(η5‑C5Ph5)Fe(CO)2][PPN],". Organometallics Journals.
Morneau, A., Geiger, W., Richmond, M. G., Don, M., Watson, W., Nagl, A. (2002). "Reduction and Oxidation of the Arachno Clusters Fe2(CO)6(μ-S)2PtL2: Characterization of Distinct One- and Two-Electron Transfer Sites in Heteropolynuclear Compounds,". Organometallics Journals.
Richmond, M. G. (2002). Annual survey of organometallic metal cluster chemistry for the year 2000. Coordination Chemistry Reviews. 228(1), 19--41. Elsevier.
Carter, B. T., Castellani, M. P., Rheingold, A. L., Hwang, S., Longacre, S. E., Richmond, M. G. (2002). Ion-Pairing Thermodynamics for ($\eta$5-pentadienyl) Fe (CO) 2-(Pentadienyl= MeCp, C5Me5, C5Ph5, C9H7) and X-ray Crystal Structure of [($\eta$5-C5Ph5) Fe (CO) 2][PPN]. Organometallics. 21(2), 373--379. ACS Publications.
Morneau, A., Geiger, W. E., Richmond, M. G., Don, M., Watson, W. H., Nagl, A. (2002). Reduction and Oxidation of the Arachno Clusters Fe2 (CO) 6 ($\mu$-S) 2PtL2: Characterization of Distinct One-and Two-Electron Transfer Sites in Heteropolynuclear Compounds. Organometallics. 21(6), 1247--1256. ACS Publications.
Bott, S., Shen, H., Richmond, M. G. (2001). "CO Substitution in PhCCo3(CO)9 by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Ligand Fluxionality, Kinetics, and X-ray Structures of PhCCo3(CO)7(bpcd) and Co3(CO)6[μ2-η2,η1-C(Ph)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2),". Structural Chemistry.
Bott, S., Shen, H., Richmond, M. G. (2001). "Ligand-Promoted Transformation of the μ3-η2-Vinylidene Ligand in the Reaction Between RuCo2(CO)9(μ3-η2-C=CHPh) and 4,5‑Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). X-ray Structure of RuCo2(CO)7(bpcd)(μ3-η2-C=CHPh),". Structural Chemistry.
Bott, S., Yang, K., Richmond, M. G. (2001). "X-ray Diffraction Structure of Re2(CO)8[(Z)-Ph2PCH=CHPPh2]. Proof for Diphosphine Ligation Across the Re-Re Bond,". Journal of Chemical Crystallography.
Richmond, M. G. (2001). Annual survey of organometallic metal cluster chemistry for the year 1999. Coordination Chemistry Reviews. 214(1), 1--42. Elsevier.
Bott, S. G., Shen, H., Richmond, M. G. (2001). CO Substitution in PhCCo3 (CO) 9 by 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Ligand Fluxionality, Kinetics, and X-Ray Structures of PhCCo3 (CO) 7 (bpcd) and $ $$\{$$\backslash$text $\{$Co$\}$$\}$ \_ $\{$$\backslash$text $\{$3$\}$$\}$($\{$$\backslash$text $\{$CO)$\}$$\}$ \_6 [$\backslash$mu \_2 $\{$$\backslash$text $\{$-$\}$$\}$$\backslash$eta\^ 2,$\backslash$eta\^ 1 $\{$$\backslash$text $\{$-C (Ph) C$\}$$\}$=$\{$$\backslash$text $\{$C (PPh$\}$$\}$ \_ $\{$$\backslash$text $\{$2$\}$$\}$)$\{$$\backslash$text $\{$C (O) CH$\}$$\}$ \_ $\{$$\backslash$text $\{$2$\}$$\}$$\{$$\backslash$text $\{$C (O)]-($\}$$\}$$\backslash$mu \_ $\{$$\backslash$text $\{$2$\}$$\}$$\{$$\backslash$text $\{$-PPh$\}$$\}$ \_ $\{$$\backslash$text $\{$2$\}$$\}$) $ $. Structural Chemistry. 12(3-4), 225--235. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Shen, H., Richmond, M. G. (2001). Ligand-Promoted Transformation of the $\mu$3-$\eta$2-Vinylidene Ligand in the Reaction between RuCo2 (CO) 9 ($\mu$3-$\eta$2-C= CHPh) and 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). X-Ray Structure of RuCo2 (CO) 7 (bpcd)($\mu$3-$\eta$2-C= CHPh). Structural Chemistry. 12(3-4), 237--242. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Yang, K., Richmond, M. G. (2001). X-ray diffraction structure of Re 2 (CO) 8 [(Z)-Ph 2 PCH= CHPPh 2]. Proof for diphosphine ligation across the Re--Re bond. Journal of Chemical Crystallography. 31(11-12), 485--489. Kluwer Academic Publishers-Plenum Publishers.
Richmond, M. G. (2000). "Organometallic Metal Cluster Chemistry for the Year 1998,". Journal of Coordination Chemistry.
Bott, S., Shen, H., Richmond, M. G. (2000). "Photochemically Mediated Alkyne Metalation in the Donor-Acceptor Complexes Ru2(CO)6(μ-P-P) [where P-P = bpcd, (Z)-Ph2PCH=CHPPh2]. X-ray Diffraction Structure of the Zwitterionic Compound Ru2(CO)6[μ-(Z)-MeO2CC=CCO2Me](μ-bpcd),". Inorganica Chimica Acta.
Bott, S., Yang, K., Wang, J., Richmond, M. G. (2000). "Selective Diphosphine Ligand Chelation and π Bond Coordination in CoRu(CO)7(μ-PPh2): Kinetics and X-ray Structure of CoRu(CO)4(μ‑bma)(μ‑PPh2),". Inorganic Chemistry.
Bott, S., Yang, K., Richmond, M. G. (2000). "X-ray Diffraction Structure of Co2(CO)4(μ-PhC º CH)[(Z)-Ph2PCH=CHPPh2]. Proof for Diphosphine Ligand Chelation,". Journal of Chemical Crystallography.
Richmond, M. G. (2000). Annual survey of organometallic metal cluster chemistry for the year 1998. Coordination Chemistry Reviews. 209(1), 333--386. Elsevier.
Bott, S. G., Shen, H., Richmond, M. G. (2000). Photochemically mediated alkyne metalation in the donor--acceptor complexes Ru 2 (CO) 6 ($\mu$-P P)[where P P= bpcd,(Z)-Ph 2 PCH CHPPh 2]. X-ray diffraction structure of the zwitterionic compound Ru 2 (CO) 6 [$\mu$-(Z)-MeO 2 CC CCO 2 Me]($\mu$-bpcd). Inorganica Chimica Acta. 300, 1077--1081. Elsevier.
Bott, S. G., Yang, K., Wang, J. C., Richmond, M. G. (2000). Selective Diphosphine Ligand Chelation and $\pi$ Bond Coordination in CoRu (CO) 7 ($\mu$-PPh2): Kinetics and X-ray Structure of CoRu (CO) 4 ($\mu$-bma)($\mu$-PPh2). Inorganic Chemistry. 39(26), 6051--6055. ACS Publications.
Bott, S. G., Yang, K., Richmond, M. G. (2000). X-ray diffraction structure of Co2 (CO) 4 ($\mu$-PhC$\equiv$ CH)[(Z)-Ph2PCH= CHPPh2 [: proof for diphosphine ligand chelation. Journal of Chemical Crystallography. 30(10), 627--632. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Nagl, A., Don, M., Richmond, M. G. (2000). X-ray diffraction structure of the phosphido-bridged mixed-metal cluster Fe2 (CO) 6 ($\mu$3-PPh) 2Pt (dppe). Journal of Chemical Crystallography. 30(4), 233--236. Kluwer Academic Publishers-Plenum Publishers.
Watson, H., Nagl, A., Don, M., Richmond, M. G. (2000). X-Ray Diffraction Structure of the Phosphido-bridged Mixed-metal Cluster Fe2(CO)6(μ3‑PPh)2Pt(dppe),". Journal of Chemical Crystallography.
Bott, S. G., Wang, J. C., Shen, H., Richmond, M. G. (1999). "Chelation of a Diphosphine Ligand at FeCo2(CO)9(μ3-S). Spectroscopic and X‑Ray Diffraction Data for FeCo2(CO)7(bpcd)(μ3-S),". Journal of Chemical Crystallography.
Bott, S., Wang, ., Richmond, M. G. (1999). "Reaction of Bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) with Ru3(CO)12. Evidence for Facile Ligand Fragmentation in Ru3(CO)10(dmpdmh) to Give Ru4(CO)12[μ-N(Me)N(Me)], Ru3(CO)11[P(OMe)3], and Ru3(CO)9[μ-P(OMe)3],". Journal of Chemical Crystallography.
Castellani, M., Smith, W., Patel, N., Bott, S., Richmond, M. G. (1999). "Reaction of Ethyl Diazoacetate with Co3(CO)9(μ3-CCl): Isolation and X‑ray Structures of Co3(CO)9(μ3-CCO2Et), Co3(CO)9(μ3-CCH2CO2Et), and [Co3(CO)9(μ3-CCHCO2Et)]2,". Journal of Chemical Crystallography.
Bott, S., Wang, J., Richmond, M. G. (1999). "Room Temperature Ligand Fragmentation in the Reaction Between PhCCo3(CO)9 and Ph2PN(Me)N(Me)PPh2. X-Ray Diffraction Structure of PhCCo3(CO)8[Ph2PP(O)Ph2],". Journal of Chemical Crystallography.
Watson, W., Nagl, A., Don, M., Richmond, M. G. (1999). "Synthesis, Redox Chemistry, and X-ray Structure of the Mixed-Metal Cluster Fe2(CO)6(μ3‑S)2Ni(dppf),". Journal of Chemical Crystallography.
Bott, S. G., Wang, J. C., Shen, H., Richmond, M. G. (1999). Chelation of a diphosphine ligand at FeCo2 (CO) 9 ($\mu$3-S): Spectroscopic and X-ray diffraction data for FeCo2 (CO) 7 (bpcd)($\mu$3-S). Journal of Chemical Crystallography. 29(4), 391--397. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Wang, J. C., Richmond, M. G. (1999). Reaction of bis (dimethoxyphosphino) dimethylhydrazine (dmpdmh) with Ru3 (CO) 12: Evidence for facile ligand fragmentation in Ru3 (CO) 10 (dmpdmh) to give Ru4 (CO) 12 [$\mu$-N (Me) N (Me)], Ru3 (CO) 11 [P (OMe) 3], and Ru3 (CO) 9 [$\mu$-P (OMe) 3]. Journal of Chemical Crystallography. 29(5), 587--595. Kluwer Academic Publishers-Plenum Publishers.
Castellani, M. P., Smith, W. G., Patel, N. G., Bott, S. G., Richmond, M. G. (1999). Reaction of ethyl diazoacetate with Co3 (CO) 9 ($\mu$3-CCl): Isolation and X-ray structures of Co3 (CO) 9 ($\mu$3-CCO2Et), Co3 (CO) 9 ($\mu$3-CCH2CO2Et), and [Co3 (CO) 9 ($\mu$3-CCHCO2Et)] 2. Journal of Chemical Crystallography. 29(5), 609--617. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Wang, J. C., Richmond, M. G. (1999). Room temperature ligand fragmentation in the reaction between PhCCo3 (CO) 9 and Ph2PN (Me) N (Me) PPh2. X-ray diffraction structure of PhCCo3 (CO) 8 [Ph2PP (O) Ph2]. Journal of Chemical Crystallography. 29(5), 603--608. Kluwer Academic Publishers-Plenum Publishers.
Watson, W. H., Nagl, A., Don, M., Richmond, M. G. (1999). Synthesis, redox chemistry, and X-ray structure of the mixed-metal cluster Fe2 (CO) 6 ($\mu$3-S) 2Ni (dppf). Journal of Chemical Crystallography. 29(8), 871--876. Kluwer Academic Publishers-Plenum Publishers.
Duffy, N. W., Nelson, R. R., Richmond, M. G., Rieger, A. L., Rieger, P. H., Robinson, B. H., Tyler, D. R., Wang, J. C., Yang, K. (1998). An EPR study of 2, 3-bis (diphenylphosphino) maleic anhydride (BMA) complexes and the BMA radical anion. Inorganic Chemistry. 37(19), 4849--4856. ACS Publications.
Richmond, M. G. (1998). Annual survey of organometallic metal cluster chemistry for the year 1997. Coordination Chemistry Reviews. 175(1), 271--322. Elsevier.
Bott, S. G., Wang, J. C., Richmond, M. G. (1998). Reaction of bis (dimethoxyphosphino) dimethylhydrazine (dmpdmh) with PhCCo 3 (CO) 9: synthesis and X-ray characterization of the dmpdmh-bridged polymorphs of PhCCo 3 (CO) 7 [(MeO) 2 PN (Me) N (Me) P (OMe) 2]. Journal of Chemical Crystallography. 28(5), 401--407. Kluwer Academic Publishers-Plenum Publishers.
Bott, S. G., Shen, H., Richmond, M. G. (1998). Regiospecific ligand addition to the donor--acceptor compound Ru 2 (CO) 6 (bpcd): syntheses and X-ray diffraction structures of Ru 2 (CO) 5 L (bpcd) and Ru 2 (CO) 5 L [$\mu$-C= C (PPh 2) C (O) CH 2 C$\}$(O)]($\mu$ 2-PPh 2)(where L= PMe 3 and t BuNC). Journal of Chemical Crystallography. 28(5), 385--399. Kluwer Academic Publishers-Plenum Publishers.
Huafeng, S., Bott, S. G., Richmond, M. G. (1998). Site-selective PMe 3 addition to the donor-acceptor complex Ru 2 (CO) 6 [(Z)-Ph 2 PCH= CHPPh 2]. X-ray diffraction structure of Ru 2 (CO) 5 (PMe 3)[(Z)-Ph 2 PCH= CHPPh 2]. Inorganica Chimica Acta. 267(2), 223--228. Elsevier Science Publishing Company, Inc..
Shen, H., Bott, S. G., Richmond, M. G. (1998). Site-selective PMe 3 addition to the donor-acceptor complex Ru 2 (CO) 6 [(Z) Ph 2 PCH CHPPh 2]. X-ray diffraction structure of Ru 2 (CO) 5 (PMe 3)[(Z) Ph 2 PCH CHPPh 2]. Inorganica Chimica Acta. 267(2), 223--228. Elsevier.
Castellani, M. P., Bott, S. G., Richmond, M. G. (1998). Synthesis of a mixed cluster/binuclear compound. Electrochemical properties and X-ray diffraction structure of Co 3 (CO) 9 [$\mu$ 3-CCO 2 CH 2 CCH $\{$Co 2 (CO) 6$\}$]. Journal of Chemical Crystallography. 28(9), 693--699. Kluwer Academic Publishers-Plenum Publishers.
Hegedus, L. S., Ortmans, I., Moucheron, C\'ecile,, Kirsch-De Mesmaeker, Andr\'ee, (1998). The compounds which are discussed in the present review are highly oxidizing Ru (II) complexes, based on various polyazaaromatic ligands, and acting as efficient electron acceptors in the excited state. The photoinduced charge transfer process and the following associated kinetic steps are characterized for the whole series of complexes by quite different techniques and methods. Thus their behaviour.... Coordination Chemistry Reviews. 168, 233--271.
Shen, H., Bott, S. G., Richmond, M. G. (1997). Acetylene substitution in the triruthenium clusters Ru3 (CO) 12-n (MeCN) n (where n= 0, 2). X-ray diffraction structures for Ru3 (CO) 9 ($\mu$2-H)($\mu$3-$\eta$2-C= CC6H4Me-4) and Ru4 (CO) 12 ($\mu$4-$\eta$2-HC= CPh). Journal of Chemical Crystallography. 27(1), 25--33. Plenum.
Shen, H., Wang, J. C., Bott, S. G., Richmond, M. G. (1997). CO replacement in Ru 3 (CO) 12 by 2, 3-bis (diphenylphosphino) maleic anhydride (bma). X-ray structures of Ru 3 (CO) 10 (bma)\textperiodcentered H 2 O and. Journal of Chemical Crystallography. 27(11), 649--656. Kluwer Academic Publishers-Plenum Publishers.
Yang, K., Martin, J. A., Bott, S. G., Richmond, M. G. (1997). Cp∗ Ru (NO)(catecholate) compounds. Synthesis, redox behavior, extended H\"uckel molecular orbital calculations, and X-ray diffraction structure of the pentamethylcyclopentadienylruthenium complex Cp∗ Ru (NO)(2, 3-naphthalenediolate)\textperiodcentered CH 2 Cl 2. Inorganica Chimica Acta. 254(1), 19--27. Elsevier.
Shen, H., Bott, S. G., Richmond, M. G. (1997). Reaction of dimethylamine with 4, 5-dichloro-4-cyclopenten-1, 3-dione: X-ray diffraction structure and cyclic voltammetric data for ClC= C (NMe2) C (O) CH2C (O). Journal of Chemical Crystallography. 27(1), 19--24. Plenum.
Don, M., Yang, K., Bott, S. G., Richmond, M. G. (1997). Redox investigation and X-ray diffraction structure of the dimeric rhodium maleonitriledithiolate complex [Cp∗ Rh (mnt)] 2. Confirmation of bridging and chelating mnt ligands in the solid-state structure. Journal of Organometallic Chemistry. 544(1), 15--21. Elsevier.
Huafeng, S., Bott, S. G., Richmond, M. G. (1996). Basal site substitution in the sulfido-bridged cluster Ru 3 (CO) 9 ($\mu$ 3-S) 2 by the redox-active diphosphine 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Synthesis, X-ray structure and electrochemical properties of Ru 3 (CO) 7 (bpcd)($\mu$ 3-S) 2. Inorganica Chimica Acta. 2(241), 71--79.
Shen, H., Bott, S. G., Richmond, M. G. (1996). Basal site substitution in the sulfido-bridged cluster Ru3 (CO) 9 ($\mu$3-S) 2 by the redox-active diphosphine 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Synthesis, X-ray structure and electrochemical properties of Ru3 (CO) 7 (bpcd)($\mu$3-S) 2. Inorganica Chimica Acta. 241(2), 71--79. Elsevier.
Yang, K., Martin, J. A., Bott, S. G., Richmond, M. G. (1996). Diyne and Phosphorus- Carbon Bond Reactivity in the Reaction between [Co2 (CO) 6] 2 (PhC4Ph) and 2, 3-Bis (diphenylphosphino) maleic Anhydride (bma). Syntheses, Molecular Orbital Properties, and X-ray Diffraction Structures of Co2 (CO) 4 [$\mu$-$\eta$2: $\eta$2: $\eta$1: $\eta$1-(Z)-Ph2P (Ph) CC (PhC2)-CC (Ph2P) C (O) OC (O)], Co2 (CO) 2 (bma) 2⊙ CH2Cl2, and Co2 (CO) 2 (bma)[$\mu$-CC (Ph2P) C (O) OC (O)]($\mu$2-Ph2P)⊙ C6H14. Organometallics. 15(9), 2227--2236. ACS Publications.
Abu-Gnim, C., Amer, I., Ando, W., Asano, K., Aupers, J., Borchert, T., Bott, S., Cabestaing, C., Chen, J., Chen, Q., others, (1996). ELSEVIER Journal of Organometallic Chemistry 516 (1996) 245. Journal of Organometallic Chemistry. 516, 245.
Shen, H., Bott, S., Richmond, M. (1996). For related fluxionality of a chelated diphosphine ligand in a Ru 3, see. Other. 241, 71.
Xia, C., Yang, K., Bott, S. G., Richmond, M. G. (1996). P- C Bond Activation and Phenyl Group Transfer in the Reaction of Co4 (CO) 9 (mesitylene) with 2, 3-Bis (diphenylphosphino) maleic Anhydride (bma). X-ray Diffraction Structures and Redox Properties of Co3 (CO) 7 [$\mu$2-$\eta$2, $\eta$1-P (Ph) CC (PPh2) C (O) OC (O)] and Co3 (CO) 6 (PPh3)[$\mu$2-$\eta$2, $\eta$1-P (Ph) CC (PPh2) C (O) OC (O)]. Organometallics. 15(21), 4480--4487. ACS Publications.
Don, M., Yang, K., Bott, S. G., Richmond, M. G. (1996). Ph2PPy REPLACEMENT OF THE 1, 5-COD LIGAND IN THE SULFIDO-CAPPED CLUSTER Fe2 (CO) 6 ($\mu$3-S) 2Pt (1, 5-COD). X-RAY DIFFRACTION STRUCTURE AND REDOX BEHAVIOR OF Fe2 (CO) 6 ($\mu$3-S) 2Pt (Ph2PPy) 2. Journal of Coordination Chemistry. 40(4), 273--284. Taylor \& Francis.
Watson, W. H., Nagl, A., Don, M., Richmond, M. G. (1996). PhPMe 2 ligand substitution in the tetracobalt cluster Co 4 (CO) 10 ($\mu$ 4-PPh) 2: X-ray diffraction structure of Co 4 (CO) 8 (PPhMe 2) 2 ($\mu$ 4-PPh) 2. Journal of Chemical Crystallography. 26(1), 75--79. Kluwer Academic Publishers-Plenum Publishers.
Yang, K., Verran, R. L., Bott, S. G., Richmond, M. G. (1996). REACTION OF Cp∗ Ru (NO) Cl2 WITH 2, 2-DICYANO-1, 1-ETHYLENEDITHIOLATE (i-mnt). REDOX CHEMISTRY AND X-RAY DIFFRACTION STRUCTURE OF Cp∗ Ru (NO)[S2C= C (CN) 2]. Journal of Coordination Chemistry. 38(1-2), 75--84. Taylor \& Francis.
Shen, H., Bott, S. G., Richmond, M. G. (1996). Reaction of FcCCo 3 (CO) 9 with 2, 3-bis (diphenylphosphino) maleic anhydride (bma). X-ray diffraction structure and redox properties of. Inorganica Chimica Acta. 250(1), 195--202. Elsevier.
Huafeng, S., Bott, S. G., Richmond, M. G. (1996). Reaction of FcCCo 3 (CO) 9 with 2, 3-bis (diphenylphosphino) maleic anhydride (bma). X-ray diffraction structure and redox properties of Co 3 (CO) 6 [$\mu$ 2-$\eta$ 2: $\eta$ 1-C (Fc) C= C (PPh 2) C (O) OC (O)]($\mu$ 2-PPh 2). Inorganica Chimica Acta. 250(1-2), 195--202. Elsevier Science Publishing Company, Inc..
Shen, H., Senter, R. A., Bott, S. G., Richmond, M. G. (1996). Regioselective and stereoselective PPh3 substitution in the imido-capped cluster Ru3 (CO) 10 ($\mu$3-NPh). Electrochemical properties and X-ray diffraction structures of Ru3 (CO) 9 (PPh3)($\mu$3-NPh) and Ru3 (CO) 8 (PPh3) 2 ($\mu$3-NPh)\textperiodcentered 12CH2Cl2. Inorganica Chimica Acta. 247(2), 161--167. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1996). Regioselective phosphine attack on the coordinated alkyne in Co2 ($\mu$-alkyne) complexes Reactivity studies and X-ray diffraction structures of Co2 (CO) 4 (bma)($\mu$-HC CtBu) and the zwitterionic hydrocarbyl complexes Co2 (CO) 4 [$\mu$-$\eta$2: $\eta$2: $\eta$1: $\eta$1-RC C (R′) PPh2C C (PPh2) C (O) OC (O)]. Journal of Organometallic Chemistry. 516(1-2), 65--80. Elsevier.
Don, M., Yang, K., Bott, S. G., Richmond, M. G. (1996). Synthesis, redox properties, and X-ray diffraction structure of the platinum catecholate complex Pt (1, 5-COD)(1, 2-O 2 C 6 H 4). Journal of Chemical Crystallography. 26(5), 335--340. Kluwer Academic Publishers-Plenum Publishers.
Yang, K., Bott, S. G., Richmond, M. G. (1996). X-ray diffraction structure of the pentamethylcyclopentadienylruthenium complex Cp* Ru (NO)(ox). Journal of Chemical Crystallography. 26(1), 5--8. Kluwer Academic Publishers-Plenum Publishers.
Yang, K., Bott, S. G., Richmond, M. G. (1995). . mu. 2-. eta. 2:. eta. 1-Benzylidene (diphenylphosphino) maleic Anhydride Mediated PMe3 Addition to the Tricobalt Cluster Co3 (CO) 6 [. mu. 2-. eta. 2:. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O)](. mu. 2-PPh2). Structure and Redox Properties of the Arachno Cluster Co3 (CO) 4 (PMe3) 2 [. mu. 2-. eta. 2:. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O)](. mu. 2-PPh2). Organometallics. 14(6), 2718--2724. ACS Publications.
Wang, D., Shen, H., Richmond, M., Schwartz, M. (1995). 13C NMR study of reorientational dynamics in Ru3 (CO) 9 ($\mu$3-CO)($\mu$3-NPh). Relaxation time analysis in the non-motional narrowing regime. Inorganica Chimica Acta. 236(1-2), 1--6. Elsevier.
Richmond, M. G. (1995). Annual survey of ruthenium and osmium for the year 1993. Coordination Chemistry Reviews. 141, 63--152. Elsevier.
Wang, D., Shen, B., Richmond, M., Schwartz, M. (1995). Carbonyl Fluxionality in the nido Cluster Ru3 (CO) 9 (. mu. 3-CO)(. mu. 3-NPh). NMR Evidence and Mechanism for the Exchange of the Triply-Bridging CO with the Terminal CO Groups. Organometallics. 14(8), 3636--3640. ACS Publications.
Xia, C., Bott, S. G., Richmond, M. G. (1995). CO substitution and diphosphine ligand chelation in the reaction between 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) and Re (2 (CO) 8 ($\mu$-H)($\mu$-$\eta$1, $\eta$2-C CPh). Inorganica Chimica Acta. 230(1-2), 45--50. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1995). Diastereoselectivity and Regioselectivity in the Intramolecular Phosphine Attack on a Coordinated Alkyne Ligand in Co2 (CO) 4 (bmf)(. mu.-PhC. tplbond. CH). Formation of the Chiral Hydrocarbyl Complex Co2 (CO) 4 [. mu.-. eta. 2,. eta. 2,. eta. 1,. eta. 1-PhC: C (H) PPh2C: C (PPh2) C (O) OCH (OMe)]. Organometallics. 14(11), 4977--4979. ACS Publications.
Wang, K., Wang, D., Yang, K., Richmond, M., Schwartz, M. (1995). Directional Effects of CO. pi. Bonding in Group VIB Pentacarbonyl Amines. Inorganic Chemistry. 34(12), 3241--3244. American Chemical Society.
Bachmann, C., Barone, V., Beatty, R., BlSser, D., Boese, R., Bolivar, A., Bonvoisin, J., Bott, S., Briiggeller, P., Byrke, M., others, (1995). ELSEVIER Inorganica Chimica Acta 238 (1995) 205. Inorganica Chimica Acta. 238, 205.
Asaro, F., Bencze, L., Blau, S., Bott, S., Castanet, Y., Chen, C., Daniel, T., Ding, K., Drtiger, M., Dreos, R., others, (1995). ELSEVIER Journal of Organometallic Chemistry 505 (1995) 139. Journal of Organometallic Chemistry. 505, 139.
Chyan, O., Chen, J., Liu, M., Richmond, M. G., Yang, K. (1995). High Surface Area Electrode Materials by Derect Metallization of Porous Substrates. Other. 393, . Cambridge University Press.
Huafeng, S., Williams, T. J., Bott, S. G., Richmond, M. G. (1995). Ligand substitution of the redox-active diphosphine 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) in the alkynyl-bridged cluster Ru 3 (CO) 9 ($\mu$ 2-H)($\mu$ 3-$\eta$ 2-C\# C t Bu). Synthesis, X-ray structure and electrochemical properties of Ru 3 (CO) 7 ($\mu$ 2-H)($\mu$ 3-$\eta$ 2-C\# C t Bu)(bpcd). Journal of Organometallic Chemistry. 505(1), 1--9. Elsevier Science Publishing Company, Inc..
Shen, H., Williams, T. J., Bott, S. G., Richmond, M. G. (1995). Ligand substitution of the redox-active diphosphine 4, 5-bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd) in the alkynyl-bridged cluster Ru3 (CO) 9 ($\mu$2-H)($\mu$3-$\nu$2-C CtBu). Synthesis, X-ray structure and electrochemical properties of Ru3 (CO) 7 ($\mu$2-H)($\mu$3-$\nu$2-C CtBu)(bpcd). Journal of Organometallic Chemistry. 505(1), 1--9. Elsevier.
Lee, S. W., Yang, K., Martin, J. A., Bott, S. G., Richmond, M. G. (1995). One-pot synthesis of CpRe (CO) 2H2 and trans-CpRe (CO) 2 (SnPh3) 2 from cis-and trans-CpRe (CO) 2Br2 and Ph3SnH. Involvement of a radical-chain sequence in the formation of CpRe (CO) 2H2. Inorganica Chimica Acta. 232(1-2), 57--62. Elsevier.
Shen, H., Bott, S. G., Richmond, M. G. (1995). Photochemically Activated Phosphorus-Carbon Bond Cleavage in the Binuclear Ruthenium Complex [cyclic] Ru2 (CO) 6 (bpcd). Redox Reactivity, Molecular Orbital Properties, and X-ray Diffraction Structures of [cyclic] Ru2 (CO) 6 (bpcd) and [cyclic] Ru2 (CO) 6 [. mu.-C: C (PPh2) C (O) CH2C (O)](. mu. 2-PPh2). Organometallics. 14(10), 4625--4634. ACS Publications.
Yang, K., Bott, S. G., Richmond, M. G. (1995). Polyhedral Cluster Expansion in Co3 (CO) 6 [. mu. 2-. eta. 2:. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O)](. mu. 2-PPh2). Characterization of the Hypho Cluster Co3 (CO) 5 (. mu.-CO)(PMe3)[. mu. 2-. eta. 2:. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O)](. mu. 2-PPh2) and the Phosphine-Substituted Arachno Cluster Co3 (CO) 5 (PMe3)[. mu. 2-. eta. 2:. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O)](. mu. 2-PPh2). Organometallics. 14(2), 919--924. ACS Publications.
Xia, C., Richmond, M. (1995). Ruthenium-TPPTS catalyzed reduction of nitrobenzene to aniline A highly selective water-soluble catalyst system. Other. 4, 393--400. CHENGDU INSTITUTE OF ORGANIC CHEMISTRY.
Shen, H., Senter, R. A., Bott, S. G., Richmond, M. G. (1995). Synthesis of the pentamethylcyclopentadienylruthenium dithiolate complex Cp∗ Ru (NO)(dmit). Electrochemical properties and extended H\"uckel molecular orbital calculations. Inorganica Chimica Acta. 238(1-2), 57--61. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1995). Synthesis, Redox Reactivity, and X-ray Diffraction Structures of the Rhenium Carbonyl Complexes fac-ReBr (CO) 3 (bma) and [fac-ReBr (CO) 3 (bma)][Cp2Co]. Structural Consequences of Electron Accession in fac-ReBr (CO) 3 (bma). Organometallics. 14(5), 2387--2394. ACS Publications.
Yang, K., Bott, S. G., Richmond, M. G. (1995). X-ray diffraction structure of the 1, 1′-bis (diphenylphosphino) ferrocene (dppf)-bridged complex [(dppf) AgCl] 2: An unexpected product from the reaction betweencis-(bpy) 2 RuCl 2 and dppf in the presence of AgBF 4. Journal of Chemical Crystallography. 25(5), 263--266. Kluwer Academic Publishers-Plenum Publishers.
Richmond, M. G. (1994). Annual survey of ruthenium and osmium for the year 1991. Journal of Organometallic Chemistry. 477(1-2), 173--217. Elsevier.
Yang, K., Chien, H., Richmond, M. G. (1994). Cylindrical internal reflectance (CIR) evidence for the facile fragmentation of PhCCO3 (CO) 7 (cis-Ph2PCH CHPPh2) during the hydroformylation of 1-pentene. Other. 88(2), 159--166. Elsevier.
Lee, S., Richmond, M. G. (1994). Hydride Reduction of diag-$($\backslash$eta5-C\_5H\_5) Re (CO) \_2Br\_2 $: Ring Attack vs. Metal-Halogen Exchange. Other. 15(11), 1013--1016. Korean Chemical Society.
Don, M., Chien, H., Richmond, M. G. (1994). Hydroformylation catalysis explored by cylindrical internal reflectance spectroscopy. Spectroscopic evidence for the fragmentation of the benzylidyne cluster PhCCo3 (CO) 9. Other. 88(2), 133--139. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1994). Intramolecular Phosphine Attack on a Coordinated Alkyne Ligand in Co2 (CO) 4 (bma)(. mu.-PhC. tplbond. CH). Characterization of the Zwitterionic Hydrocarbyl Complex Co2 (CO) 4 [. mu.-. eta. 2:. eta. 2:. eta. 1:. eta. 1-PhC: C (H) PPh2C: C (PPh2) C (O) OC (O)]. Organometallics. 13(10), 3767--3769. American Chemical Society.
Yang, K., Bott, S. G., Richmond, M. G. (1994). Reversible Chelate-to-Bridge Ligand Exchange in Co2 (CO) 4 (. mu.-PhC. tplbond. CPh)(bma) and Alkyne-Diphosphine Ligand Coupling. Synthesis, Reactivity, and Molecular Structures of Co2 (CO) 4 (. mu.-PhC. tplbond. CPh)(bma), Co2 (CO) 4 (. mu.-PhC. tplbond. CPh)$\{$(Z)-Ph2PCH: CHPPh2$\}$, and Co2 (CO) 4 $\{$. eta. 2,. eta. 2,. eta. 1,. eta. 1-(Z)-Ph2PC (Ph):(Ph) CC: C (PPh2) C (O) OC (O)$\}$. Organometallics. 13(10), 3788--3799. ACS Publications.
Xia, C., Bott, S. G., Richmond, M. G. (1994). Synthesis, molecular structure and electrochemical investigation of the 1, 2, 5-thiadiazole-3, 4-dithiolate-substituted complex Cp* Ru (NO)(tdas). Evidence for nitrosyl bending during reduction. Inorganica Chimica Acta. 226(1-2), 267--274. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1994). Synthesis, X-ray crystal structure, and redox properties of Cp* Ru (NO)(mnt). Journal of Organometallic Chemistry. 483(1-2), 7--15. Elsevier.
Watson, W. H., Nagl, A., Hwang, S., Richmond, M. G. (1993). 1, 1′-Bis (diphenylphosphino) ferrocene ligand substitution in the benzylidyne-capped cluster PhCCo3 (CO) 9. Synthesis, X-ray structure, and redox reactivity of PhCCo3 (CO) 7 (dppf). Journal of Organometallic Chemistry. 445(1-2), 163--170. Elsevier.
Richmond, M. G. (1993). Annual survey of ruthenium and osmium for the year 1990. Journal of Organometallic Chemistry. 457(1-2), 121--165. Elsevier.
Yang, K., Bott, S. G., Richmond, M. G. (1993). Bidentate ligand substitution in PhCCo3 (CO) 9. Synthesis, molecular structure, and redox reactivity of PhCCo3 (CO) 7 (cis-Ph2PCH CHPPh2. Journal of Organometallic Chemistry. 454(1-2), 273--280. Elsevier.
Yang, K., Smith, J. M., Bott, S. G., Richmond, M. G. (1993). Phosphorus-carbon bond cleavage and tetrahedrane cluster activation in the reaction between bis (diphenylphosphino) maleic anhydride (BMA) and PhCCo3 (CO) 9. Syntheses, kinetic studies, and x-ray diffraction structures of PhCCo3 (CO) 7 (bma) and [cyclic] Co3 (CO) 6 (. mu. 2-. eta. 2,. eta. 1-C (Ph) C: C (PPh2) C (O) OC (O))(. mu. 2-PPh2). Organometallics. 12(12), 4779--4787. ACS Publications.
Don, M., Richmond, M. G. (1993). Synthesis of the thermally unstable arachno cluster Fe2 (CO) 6 ($\mu$3-S) 2Ni (1, 5-COD observation of facile decomposition to FeNiS. Inorganica Chimica Acta. 210(1), 129--130. Elsevier.
Kaiyuan, Y., Smith, J. M., Bott, S. G., Richmond, M. G. (1993). Tetrahedrane cluster and phosphorus ligand activation in the reaction between PhCCo 3 (CO) 9 and 2, 3-bis (diphenylphosphino) maleic anhydride. Molecular structure of Co 3 (Co) 6 ($\mu$ 2-$\eta$ 2-$\eta$ 1-C (Ph) C C (PPh2) C (O) OC (O))($\mu$ 2-PPh 2). Inorganica Chimica Acta. 212(1), 1--3. Elsevier.
YANG, K., Smith, J., Bott, S., Richmond, M. (1993). Tetrahedrane cluster and phosphorus ligand activation in the reaction between PhCCo3 (CO) 9 and 2, 3-bis (diphenylphosphino) maleic anhydride. Molecular structure of Co3 (CO) 6 ($\mu$2-$\eta$2-$\eta$1-C (Ph) C= C (PPh2) C (O) OC (O))($\mu$2-PPh2). Inorganica Chimica Acta. 212(1-2), 1--3. Elsevier.
RICHMOND, M. (1992). Annual survey of ruthenium and osmium for the year 1989. Other. 23(43), . WILEY-VCH Verlag.
Yuan, P., Don, M., Richmond, M., Schwartz, M. (1992). Carbon-13 NMR study and observation of restricted phenyl rotation in the cobalt alkyne complex Co2 (CO) 6 (. mu.-PhC. tplbond. CH). Inorganic Chemistry. 31(16), 3491--3492. American Chemical Society.
Don, M., Richmond, M. G. (1992). In situ cluster stability studies explored by cylindrical internal reflectance (CIR) spectroscopy: 1-pentene hydroformylation using phosphine-substituted Co4 (CO) 8P2 ($\mu$4-PPh) 2 clusters. Other. 73(2), 181--189. Elsevier.
Tassell, S., Pourshafie, M., Wright, E., Richmond, M., Barrow, W. (1992). Modified lymphocyte response to mitogens induced by the lipopeptide fragment derived from Mycobacterium avium serovar-specific glycopeptidolipids.. Other. 60(2), 706--711. Am Soc Microbiol.
Wang, S., Richmond, M., Schwartz, M. (1992). NMR evidence for the existence of a. pi.-accepting PMe3 ligand. Estimates of the magnitude of. pi. effects of WL (CO) 5 complexes. Journal of the American Chemical Society. 114(19), 7595--7596. ACS Publications.
Yuan, P., Richmond, M., Schwartz, M. (1992). Relaxation mechanisms, bonding, and molecular reorientation in CpRe (CO) 3. Journal of Organometallic Chemistry. 424(3), 331--341. Elsevier.
Richmond, M. G. (1991). Annual survey of ruthenium and osmium for the year 1988. Journal of Organometallic Chemistry. 404(1-3), 213--324. Elsevier.
Yuan, P., Richmond, M., Schwartz, M. (1991). Barrier to internal rotation in a heterometallic tetrahedrane cluster. NMR evidence for metal cluster-aryl orbital overlap. Inorganic Chemistry. 30(3), 588--590. ACS Publications.
Don, M., Richmond, M. G., Watson, W. H., Krawiec, M., Kashyap, R. P. (1991). Bis (dimethylphosphino) ethane substitution in PhCCo3 (CO) 9: Synthesis and X-ray structure of the phosphine-bridged cluster PhCCo3 (CO) 7 (dmpe). Journal of Organometallic Chemistry. 418(2), 231--239. Elsevier.
Yuan, P., Don, M., Richmond, M., Schwartz, M. (1991). Carbon-13 NMR study of a [cobalt-nickel] Co2Ni tetrahedral cluster. Preferential. pi.-orbital overlap and reorientational dynamics in Co2NiCp (CO) 6 (. mu. 3-CPh). Inorganic Chemistry. 30(19), 3704--3707. ACS Publications.
Don, M. J., Richmond, M. G. (1991). Nucleophilic discrimination in a mixed-metal phosphinidene-capped cluster. Formation of phosphido and cobalt-acyl derivatives. Inorganic Chemistry. 30(8), 1703--1709. American Chemical Society.
LEE, S. W., Richmond, M. (1991). REACTION OF HYDRIDE WITH (ETA 5-C9H7) RE (CO) 3. FACILE FORMATION OF H6RE4 (CO) 122-AND INDENIDE. Inorganic Chemistry. 30(9), 2237--2239. American Chemical Society.
Don, M., Richmond, M., Watson, W., Kashyap, R. (1991). Reaction of PhCCo3 (CO) 9 with bis (dimethylphosphino) ethane and structure of PhCCo3 (CO) 5 (dmpe) 2.(toluene). Observation of phosphine bridging and chelation. Other. 47(1), 20--23. International Union of Crystallography.
Yuan, P., Richmond, M., Schwartz, M. (1991). Reorientational dynamics and the barrier to internal rotation in Cp2Co3 (. mu. 2-CO)(CO) 3 (. mu. 3-CPh). Inorganic Chemistry. 30(4), 679--683. American Chemical Society.
LEE, S. W., Tucker, W., Richmond, M. (1990). Competitive CO attack in Fe (CO) 5 using methanolic [Et4N][OH]. IR spectral observation and reactivity studies of [Fe (CO) 4 (CO2X)-](X= OH, OMe). Inorganic Chemistry. 29(16), 3053--3056. American Chemical Society.
Silva-Avalos, J., Richmond, M. G., Nagappan, O., Kunz, D. A. (1990). Degradation of the metal-cyano complex tetracyanonickelate (II) by cyanide-utilizing bacterial isolates.. Applied and Environmental Microbiology. 56(12), 3664--3670. American Society for Microbiology.
Lee, S. W., Tucker, W. D., Richmond, M. G. (1990). Infrared evidence for competitive [Li+] and Et3B coordination to [Fe (CO) 4CHO-] and thermodynamic evaluation of the ion pair equilibrium. Journal of Organometallic Chemistry. 398(1-2), C6--C10. Elsevier.
Nunn, C. M., Cowley, A. H., Lee, S. W., Richmond, M. G. (1990). Reduction pathways in lateral and diagonal (. eta. 5-C5Me5) Re (CO) 2Br2. Synthesis, structure, and reactivity of [(. eta. 5-C5Me5) Re (CO) 2Br-]. Inorganic Chemistry. 29(11), 2105--2112. American Chemical Society.
Partin, J. A., Richmond, M. G. (1990). Site selectivity and competitive CO attack in Co4 (CO) 10 ($\mu$4-PPh) 2 using methanolic [Et4N][OH]. Journal of Organometallic Chemistry. 396(2-3), 339--353. Elsevier.
Don, M., Richmond, M. G. (1990). Synthesis and redox reactivity of the thermally unstable mixed-metal arachno cluster Fe2 (CO) 6 ($\mu$3-S) 2Cu ($\eta$5-Cp*). Inorganica Chimica Acta. 173(1), 61--64. Elsevier.
Richmond, M. G. (1989). 1-pentene hydroformylation using the mixed-metal cluster Fe2Co2 (Co) 11 ($\mu$4-PPh) 2: cylindrical internal reflectance evidence for cluster catalysis. Other. 54(2), 199--204. Elsevier.
SCHWARTZ, M., RICHMOND, M., CHEN, A., MARTIN, G., KOCHI, J. (1989). 13C Relaxation and Reorientational Dynamics in a Bicapped Tetracobalt Cluster.. Other. 20(14), . Wiley Online Library.
Wang, S., Chen, A., Richmond, M., Schwartz, M. (1989). Carbon-13 relaxation and phenyl group rotation in a benzylidyne-capped tricobalt cluster. Journal of Organometallic Chemistry. 371(1), 81--86. Elsevier.
Richmond, M. G., Pittman, Jr, C. U. (1989). Photochemical and photocatalytic studies of fluorophosphine-bridged iron and cobalt dimers. Other. 53(1), 79--103. Elsevier.
Schulman, C. L., Richmond, M. G., Watson, W. H., Nagl, A. (1989). Reaction of bis (dimethylphosphino) ethane with the tetracobalt cluster Co4 (CO) 10 ($\mu$4-PPh) 2; synthesis, structure, and solution dynamics of Co4 (CO) 8 ($\mu$4-PPh) 2 (dmpe). Journal of Organometallic Chemistry. 368(3), 367--384. Elsevier.
Don, M., Richmond, M. G., Watson, W. H., Nagl, A. (1989). Reaction of Ph2PH with the tetracobalt cluster Co4 (CO) 10 ($\mu$4-PPh) 2. Kinetic studies of sequential CO replacement and X-ray crystal structure of Co4 (CO) 8 ($\mu$4-PPh) 2 (Ph2PH) 2. Journal of Organometallic Chemistry. 372(3), 417--435. Elsevier.
Dumond, D. S., Seonggyu, H., Richmond, M. G. (1989). Synthesis and reactivity of the polynuclear formyl cluster PhCCO3 (CO) 8 (CHO)-. Evidence for facile metalloformyl C H bond scission. Inorganica Chimica Acta. 160(2), 135--137. Elsevier.
Don, M., Richmond, M., Watson, W., Nagl, A. (1989). The structure of [Co4 (CO) 8 ($\mu$4-PPh) 2 $\{$P (OEt) 3$\}$ 2]. Further evidence for thermodynamic product control in ligand substitution reactions involving Co4 (CO) 10 ($\mu$4-PPh) 2. Other. 45(5), 736--739. International Union of Crystallography.
Schwartz, M., Richmond, M., Chen, A., Martin, G., Kochi, J. K. (1988). Carbon-13 relaxation and reorientational dynamics in a bicapped tetracobalt cluster. Inorganic Chemistry. 27(26), 4698--4703. American Chemical Society.
Partin, J. A., Richmond, M. G. (1988). Hydride addition to Ru3 (CO) 12. Synthesis and characterization of the transient formyl cluster complex Ru3 (CO) 11 (CHO)-. Journal of Organometallic Chemistry. 353(1), C13--C16. Elsevier.
Dumond, D. S., Richmond, M. G. (1988). Synthesis of the transient formyl complex [CH3N (PF2) 2] 3Co2 (CO)(CHO)-and observation of facile formyl decomposition to give the mixed-valence complex [CH3N (PF2) 2] 3Co2 (CO) 2. cntdot.-. Journal of the American Chemical Society. 110(22), 7547--7549. ACS Publications.
Richmond, M., Kochi, J. (1987). Ligand bridging and chelation of tetracobalt clusters with difunctional phosphines. Organometallics. 6(2), 254--265. American Chemical Society.
Richmond, M., Kochi, J. (1987). Nucleophilic additions to carbonyl ligands on tetracobalt clusters. Formation of polynuclear formyl and carbene complexes. Organometallics. 6(4), 777--788. American Chemical Society.
Richmond, M., Kochi, J. (1987). Site selectivity in carbonyl reduction of mixed Fe2Co2 clusters. Formyl intermediates in the formation of hydrido derivatives. Journal of Organometallic Chemistry. 323(2), 219--232. Elsevier.
Richmond, M., Kochi, J. (1986). Oxidation-reduction and the electrocatalytic ligand substitution of tetracobalt clusters. Inorganic Chemistry. 25(5), 656--665. American Chemical Society.
Richmond, M., Kochi, J. (1986). Structures and mechanism of multiple ligand substitutions in bicapped tetracobalt clusters. Inorganic Chemistry. 25(9), 1334--1345. American Chemical Society.
Richmond, M. G., Korp, J. D., Kochi, J. K. (1985). Ligand-induced scission of the metal--metal bond in a bicapped tetracobalt cluster. Other. (16), 1102--1103. Royal Society of Chemistry.
Banach, D., Evans, II, G., McIntyre, D., Predmore, T., Richmond, M., Supple, J., Stewart, Jr, R. (1985). Rhodium-catalyzed hydroformylations of unsaturated nitrogen heterocycles: regio-and stereoselectivity in the synthesis of tropane and pdperidine carboxaldehydes. Other. 31(1), 15--37. Elsevier.
Pittman, Jr, C. U., Honnick, W., Richmond, M. G., Bender, R., Braunstein, P., others, (1985). The catalytic activity of low oxidation state platinum-and palladium-containing mixed-metal clusters. Other. 32(2), 177--190. Elsevier.
Richmond, M. G., Pittman, Jr, C. U., others, (1984). Metal cluster catalysis; hydroformylation using mixed-metal tetrahedrane clusters. Other. 22(3), 367--371. Elsevier.
PITTMAN, C. J., Richmond, M., ABSI-HALABI, M., Beurich, H., Richter, F., Vahrenkamp, H. (1983). Metal cluster catalysis. Part 5. Photoinitiated hydrosilylation in the presence of tetrahedral heterometal clusters: catalysis by intact clusters. Other. 14(2), . WILEY-VCH Verlag GmbH.
Pittman, C. U., Richmond, M. G., Absi-Halabi, M., Beurich, H., Richter, F., Vahrenkamp, H. (1982). Photoinitiated Hydrosilations in Presence of Tetrahedral Heterometallic Clusters: Catalysis by Intact Clusters. Angewandte Chemie International Edition. 21(10), 786--787. H\"uthig \& Wepf Verlag.
Pittman, C. U., Richmond, M. G., Absi-Halabi, M., Beurich, H., Richter, F., Vahrenkamp, H. (1982). Photoinitiierte Hydrosilylierung in Gegenwart tetraedrischer Heterometallcluster: Katalyse durch intakte Cluster. Other. 94(10), 805--806. Wiley Online Library.
Ph.D. Thesis
Lin, C. (2013). Synthetic and structural chemistry of ligand-substituted triosmium clusters and a rhenium (I) complex. University of North Texas.
Yang, L. (2010). Syntheses, X-ray Diffraction Structures, and Kinetics on New Formamidinate-substituted Triosmium Clusters. University of North Texas.
Awarded Grants
Contracts, Grants and Sponsored Research
Grant - Research
Richmond, M. G. (Principal), "TRIP match for Welch Grant B-1093," Sponsored by State of Texas, State, $45000 Funded. (September 2018 – Present).
Slaughter, L. M., D'Souza, F., Omary, M. A., Richmond, M. G., Wang, H., "MRI: Acquisition of a Microfocus X-Ray Diffractometer as a Regionwide Resource for Chemistry and Materials Research," Sponsored by National Science Foundation, Federal, $262689 Funded. (August 15, 2017 – July 31, 2020).
Sponsored Research
Richmond, M. G. (Principal), "Synthesis and Reactivtiy Studies of Metal Clusters," Sponsored by The Robert A. Welch Foundation, Private, $250000 Funded. (June 1, 2017 – May 31, 2020).
| Overall Summative Rating |
Challenge and Engagement Index |
Response Rate |
|---|---|---|
out of 5 |
out of 7 |
% of students responded |
- Overall Summative Rating (median):
This rating represents the combined responses of students to the four global summative items and is presented to provide an overall index of the class’s quality. Overall summative statements include the following (response options include a Likert scale ranging from 5 = Excellent, 3 = Good, and 1= Very poor):- The course as a whole was
- The course content was
- The instructor’s contribution to the course was
- The instructor’s effectiveness in teaching the subject matter was
- Challenge and Engagement Index:
This rating combines student responses to several SPOT items relating to how academically challenging students found the course to be and how engaged they were. Challenge and Engagement Index items include the following (response options include a Likert scale ranging from 7 = Much higher, 4 = Average, and 1 = Much lower):- Do you expect your grade in this course to be
- The intellectual challenge presented was
- The amount of effort you put into this course was
- The amount of effort to succeed in this course was
- Your involvement in course (doing assignments, attending classes, etc.) was